The value of γ(=(C_p)/(C_V)) for hydrogen, helium and another ideal...

The poisson's ratio, $$\gamma=\frac{\mathrm{C}_{\mathrm{P}}}{\mathrm{C}_{\mathrm{V}}}$$ where, $C_p=$ molar heat capacity constant pressure and $\mathrm{C}_{\mathrm{V}}=$ molar heat capacity at constant volume Also, $C_p=C_V+R$ (from Mayer's relation) $C_V=\frac{f}{2} \mathrm{R} \quad$ (where, $\mathrm{f}=$ degree of freedom) $$\Rightarrow \quad \mathrm{C}_{\mathrm{p}}=\left(\frac{\mathrm{f}}{2}+1\right) \mathrm{R}$$ So, Eq. (i) becomes, $$\Rightarrow \quad \gamma=1+\frac{2}{f}$$ For hydrogen gas, which is diatomic, the degree of freedom is 5 ( 3 translational, 2 rotational). $$\therefore \quad \gamma=1+\frac{2}{5}=\frac{7}{5}$$ For helium gas, which is monoatomic, the degree of freedom is 3 ( 3 translational only). $$\therefore \quad \gamma=1+\frac{2}{3}=\frac{5}{3}$$ The diatomic gas $\mathrm{X}$ also have vibrational motion, so degree of freedom is 7 ( 3 translational, 2 rotational and 2 vibrational). $$\therefore \quad \gamma=1+\frac{2}{7}=\frac{9}{7}$$