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NEST2022ChemistryCoordination Compounds

The correct statement(s) about [ MnCl ₆ ]⁴⁻, [ Mn ( CN )₆ ]³⁻ and [ MnCl ₄ ]²⁻ is/are

Options

  1. AAll these complexes have center of symmetry.
  2. BAccording to the Valence Bond Theory (VBT), the hybridization of Mn in [ MnCl ₆ ]⁴⁻ and that in [ Mn ( CN )₆ ]
  3. CThe d-d electronic transition is possible in [ MnCl ₆ ]⁴⁻, [ Mn ( CN )₆ ]³⁻ and [ MnCl ₄ ]²⁻ .
  4. DThe spin-only magnetic moments of the metal ions in [ MnCl ₆ ]⁴⁻ and [ MnCl ₄ ]²⁻ are equal.

Correct answer

D. The spin-only magnetic moments of the metal ions in [ MnCl ₆ ]⁴⁻ and [ MnCl ₄ ]²⁻ are equal.

Step-by-step solution

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