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NEST2022ChemistryCoordination Compounds

Two isomers of [ CoCl ₃ ( NH ₂ CH ₂ CH ₂ NHCH ₂ CH ₂ NH ₂ ) ] are shown below The correct statement about Isomer-1 and Isomer-2 is

Options

  1. AIsomer-1 and Isomer-2 are facial and meridional, respectively.
  2. BIn Isomer-1 and Isomer-2, all Cl - Co - Cl and N - Co - N bond angles are 90^ .
  3. CNeutral aqueous solution of both these isomers will react with Ag ⁺ ion to give AgCl .
  4. DIn Isomer-2, two Cl - Co - Cl bond angles are 180^ .

Correct answer

A. Isomer-1 and Isomer-2 are facial and meridional, respectively.

Step-by-step solution

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