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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Chemical Equilibrium

NTA Abhyas 2020 · Chemistry · Chemical Equilibrium

For A + B ⇌ C + D , if initially the concentration of A and B are...

For A+B⇌C+DA + B ⇌ C + D , if initially the concentration of A\text{A} and B\text{B} are equal but at equilibrium concentration of D\text{D} will be twice of that of A\text{A} then what will be the equilibrium constant of C+D⇌A+BC + D ⇌ A + B reaction ?For A + B ⇌ C + D , if initially the concentration of A and B are equal but at equilibrium concentration of D will be

Options

  1. A94\dfrac{9}{4}
  2. B97\dfrac{9}{7}
  3. C14\dfrac{1}{4}
  4. D44

Correct answer

C. 14\dfrac{1}{4}

Step-by-step solution

For A + B ⇌ C + D , if initially the concentration of A and B are equal but at equilibrium concentration of D will be
x=2(a−x)<br/>3x=2a\text{x} = 2 \left(\text{a} - \text{x}\right)<br />3x = 2a
x=2a3<br/>x = \dfrac{2a}{3}<br />{K}_{c} x⋅x(a–x)(a–x)=4a29×a3×a3=4\dfrac{\text{x} ⋅ \text{x}}{\left(\text{a} – \text{x}\right)\left(\text{a} – \text{x}\right)} = \dfrac{4a^{2}}{9 \times \dfrac{a}{3} \times \dfrac{a}{3}} =4
C+D⇌A+B;Kc=14\text{C}\text{+}\text{D} ⇌ \text{A}\text{+}\text{B;}{K}_{c} = \dfrac{1}{4}
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