NTA Abhyas 2020
- Exam
- NTA Abhyas
- Year
- 2020
- Subject
- Chemistry
- Chapter
- Chemical Equilibrium
NTA Abhyas 2020 · Chemistry · Chemical Equilibrium
The dissociation equilibrium of a gas AB_ 2 can be represented as,...
The dissociation equilibrium of a gas {\text{AB}_{2} can be represented as,
\text{2}{\text{AB}_{2} \text{(g)} ⇌ \text{2}\text{AB(g)} + {B}_{2} \text{(g)}
The degree of dissociation is and is small as compared to . The expression relating the degree of dissociation with equilibrium constant and total pressure is:
\text{2}{\text{AB}_{2} \text{(g)} ⇌ \text{2}\text{AB(g)} + {B}_{2} \text{(g)}
The degree of dissociation is and is small as compared to . The expression relating the degree of dissociation with equilibrium constant and total pressure is:
Options
- A{{\text{(2K}_{p} \text{/P)}^{\dfrac{1}{2}}
- B
- C{\text{2K}_{p} \text{/P}
- D{{\text{(2K}_{p} \text{/P)}^{\dfrac{1}{3}}
Correct answer
D. {{\text{(2K}_{p} \text{/P)}^{\dfrac{1}{3}}
Step-by-step solution
& & & & & & & 2 {AB }_{2} \left(\text{g}\right)⇌ 2AB \left(\text{g}\right) + {B }_{2}\left( g \right)
At equilibrium \text{2(1} - \text{x)}\text{2x}\text{x}
Total moles = \text{(2}\text{+}\text{x)}
Partial pressures
{P}_{{\text{AB}_{2}} \text{=}\dfrac{\text{2(1} - \text{x)}}{\text{2}\text{+}\text{x}} \text{p,}{P}_{\text{AB}} \text{=}\left(\dfrac{}{}\right) \text{p,}{P}_{{B}_{2}} \text{=}\left(\dfrac{x}{}\right) \text{p}
{K}_{p} = \dfrac{\text{p}{AB}^{2} {pB}_{2}}{( {pAB}_{2} {)}^{2}} = \dfrac{[ (){]}^{2} [ \dfrac{x \text{p}}{2 + x} ]}{[ {]}^{2}}{K}_{p} = \dfrac{4x^{3} \text{P}}{4 \left(2 + \text{x}\right){( 1- \text{x})}^{2}}
\left(2 + $\right) \to2( is small)
\left(1 - \text{x}\right) \to1
{K}_{P} = \dfrac{4x^{3} \text{p}}{8} = \dfrac{x^{3} \text{p}}{2}
=\dfrac{2 }{$p}3
At equilibrium \text{2(1} - \text{x)}\text{2x}\text{x}
Total moles = \text{(2}\text{+}\text{x)}
Partial pressures
{P}_{{\text{AB}_{2}} \text{=}\dfrac{\text{2(1} - \text{x)}}{\text{2}\text{+}\text{x}} \text{p,}{P}_{\text{AB}} \text{=}\left(\dfrac{}{}\right) \text{p,}{P}_{{B}_{2}} \text{=}\left(\dfrac{x}{}\right) \text{p}
{K}_{p} = \dfrac{\text{p}{AB}^{2} {pB}_{2}}{( {pAB}_{2} {)}^{2}} = \dfrac{[ (){]}^{2} [ \dfrac{x \text{p}}{2 + x} ]}{[ {]}^{2}}{K}_{p} = \dfrac{4x^{3} \text{P}}{4 \left(2 + \text{x}\right){( 1- \text{x})}^{2}}
\left(2 + $\right) \to2( is small)
\left(1 - \text{x}\right) \to1
{K}_{P} = \dfrac{4x^{3} \text{p}}{8} = \dfrac{x^{3} \text{p}}{2}
=\dfrac{2 }{$p}3