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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Chemical Equilibrium

NTA Abhyas 2020 · Chemistry · Chemical Equilibrium

1mole of N _ 2 O _ 4 ( g ) at 300K is kept in a closed container...

1mole\text{1}\text{mole} of N2O4(g){N}_{2}{O}_{4} ( g ) at 300K\text{300}\text{K} is kept in a closed container under 1atm\text{1}\text{atm}. It is heated to 600K\text{600}\text{K} when \text{20%} by mole of N2O4(g){N}_{2}{O}_{4} ( g ) decomposes to NO2(g)N{O}_{2} ( g ). The resultant pressure is

Options

  1. A1.2 atm
  2. B2.4 atm
  3. C2.0 atm
  4. D1.0 atm

Correct answer

B. 2.4 atm

Step-by-step solution

\begin{cases} & {N}_{2} {O}_{4} \text{(g)} & ⇌ & {\text{2NO}_{2} \text{(g)} \\ \text{Initial}\text{mole} & 1 & & 0 \\ \text{At}\text{equi}\text{.} & \text{(1-0}\text{.20)}\text{mole} & & \text{0}\text{.40}\text{mole}\end{cases}
ntotal=1.2{n}_{\text{total}} \text{=}\text{1}\text{.2}
Ptotal=ntotalRTV=2.4atm{P}_{\text{total}} \text{=}\dfrac{{n}_{\text{total}} \text{RT}}{V} \text{=}\text{2}\text{.4}\text{atm}
as P2P1=n2T2n1T1\dfrac{{P}_{2}}{{P}_{1}} \text{=}\dfrac{{n}_{2} {T}_{2}}{{n}_{1} {T}_{1}}
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