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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Chemical Equilibrium

NTA Abhyas 2020 · Chemistry · Chemical Equilibrium

Equilibrium constant for reaction N H _ 4 OH (aq) + dH ^ ⊕ (aq) ⇌ N...

Equilibrium constant for reaction NH4OHN{H}_{4}OH\left(aq\right) + {dH}^{⊕}\left(aq\right) ⇌ N{H}_{4}^{+}\left(aq\right) + {H}_{2}O\left(l\right)is1.8is 1.8\times 1{0}^{9}.Henceequilibriumconstantforionization. Hence equilibrium constant for ionizationN{H}_{3} + {H}_{2}O ⇌ N{H}_{4}^{+}\left(aq\right) + O{H}^{-}\left(aq\right)x \times 1{0}^{- 6} is.The value of ‘x’ is.

Correct answer

18

Step-by-step solution

NH4OH(aq){NH}_{4}OH\left(aq\right) + {H}^{+}\left(aq\right)⇌NH4+(aq)⇌ {NH}_{4}^{+}\left(aq\right) + {H}_{2}O\left(l\right)</p><p></p><p>{K}_{1} = \dfrac{\left[\overset{+}{N}{H}_{4}\right]}{\left[{NH}_{4}OH\right]\left[{H}^{+}\right]} = 1 .8 \times {10}^{9}</p><p></p><p>{NH}_{4}OH\left(aq\right) ⇌ {NH}_{4}^{+}\left(aq\right) + {OH}^{-}\left(aq\right)</p><p></p><p>{K}_{2} = \dfrac{\left[{NH}_{4}^{+}\right]\left[{OH}^{-}\right]}{\left[{NH}_{4}OH\right]}</p><p>Multiplythisby[H+]</p><p>Multiply this by \left[{H}^{+}\right] and divide also

K2=[NH4+][OH−][H+][NH4OH][H+]=K1×Kw{K}_{2} = \dfrac{\left[{NH}_{4}^{+}\right]\left[{OH}^{-}\right]\left[{H}^{+}\right]}{\left[{NH}_{4}OH\right]\left[{H}^{+}\right]} = {K}_{1} \times {K}_{w}

=1.8×109×1.0×10−14=18×10−6= 1 .8 \times {10}^{9} \times 1 .0 \times {10}^{- 14} = 18 \times {10}^{- 6}

value of x = 18.
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