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The equilibrium, N H 4 H S ( s ) ⇌ N H 3 ( g ) + H 2 S ( g ) , is followed to set-up at 127 ° C in a closed vessel. The total pressure at equilibrium was 20 atm. The K C for the reaction is

Options

  1. A0.092 M 2
  2. B0.085 M 2
  3. C3.045 M 2
  4. DNone of these

Correct answer

A. 0.092 M 2

Step-by-step solution

p N H 3 = p H 2 S = 20 2 = 10 atm K P = p N H 3 × p H 2 S = 100 at m 2 K P = K C ( R T ) Δ n 100 = K C ( 0.0821 × 400 ) 2 K C = 0.092 M 2 .

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