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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

NTA Abhyas 2020 · Chemistry · Haloalkanes and Haloarenes

How many of the statement(s) are correct i) The nucleophile makes a...

How many of the statement(s) are correct
i) The nucleophile makes a rear attack in SN2{S}_{N} \text{2} reaction and expels the leaving group from front side.
ii) CH3O−CH=CH2C{H}_{3}O - CH = C{H}_{2} adds to HBr\text{HBr} according to Anti‐Markownikoff’s rule.
iii) The basicity of halides decreases in the order F−>C1−>Br−>I−,F^{-} > C{1}^{-} > Br^{-} > I^{-}, but the nucleophillicity is reverse of it. (in polar protic solvents)
iv) The rate of SN2{S}_{N} \text{2} reaction is independent of the polarity of the solvent.
v) Sigma complex or arenium ion is resonance stablised.

Correct answer

3

Step-by-step solution

i) The nucleophile makes a rear attack in SN2{S}_{N} \text{2} reaction and expels the leaving group from front side.
iii) The basicity of halides decreases in the order F−>C1−>Br−>I−,F^{-} > C{1}^{-} > Br^{-} > I^{-}, but the nucleophillicity is reverse of it. (in polar protic solvents)
v) Sigma complex or arenium ion is resonance stablised.
The above statements are correct.
CH3O−CH=CH2C{H}_{3}O - CH = C{H}_{2} adds to HBr\text{HBr} according to Markownikoff’s rule.
iv) The rate of SN2{S}_{N} \text{2} reaction is faster in polar aprotic solvent.
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