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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

NTA Abhyas 2020 · Chemistry · Haloalkanes and Haloarenes

When the concentration of alkyl halide is tripled and concentration...

When the concentration of alkyl halide is tripled and concentration of nucleophile is reduced to half, the rate of SN2{S}_{N}2 reaction is increased by

Options

  1. A3 times
  2. B1.5 times
  3. C2 times
  4. D6 times

Correct answer

B. 1.5 times

Step-by-step solution

Rate of SN2{S}_{N}2 reaction is as follows:
Rate = [alkyl halide] ×\times [nucleophile]
Rate (initially) =[C1][C2]<br/>Atnewconcentration<br/>= \left[{C}_{1}\right] \left[{C}_{2}\right]<br />At new concentration<br /> Rate \left(finally\right) =\left[3{C}_{1}\right](C22)=1.5×([C1][C2])\left(\dfrac{{C}_{2}}{2}\right) =1.5 \times \left(\left[{C}_{1}\right]\left[{C}_{2}\right]\right)
\text{Rate} \left(\text{final}\right)\text{=}\text{1}\text{.5}\text{\times}\text{Rate}\left(\text{initial}\right)
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