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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Redox Reactions

NTA Abhyas 2020 · Chemistry · Redox Reactions

0.1MKMn O _ 4 is used for following titration. What volume of the...

0.1MKMnO40.1MKMn{O}_{4} is used for following titration. What volume of the solution in mLmL will be required to react with 0.158g0.158 g of Na2S2O3{Na}_{2}{S}_{2}{O}_{3}?
Not balanced: S2O32−+MnO4−+H2O→MnO2(s)+SO42−+OH−{S}_{2}{O}_{3}^{2 -} + Mn{O}_{4}^{-} + {H}_{2}O \to Mn{O}_{2 ( s )} + S{O}_{4}^{2 -} + OH^{-}

Options

  1. A26.7 mL
  2. B50 mL
  3. C65 mL
  4. D75 mL

Correct answer

A. 26.7 mL

Step-by-step solution

S+22O32−+MnO4−+H2O→MnO2(s)+S+6O42−+OH−{\overset{+ 2}{S}}_{2}{O}_{3}^{2 -} + Mn{O}_{4}^{-} + {H}_{2}O \to Mn{O}_{2 ( s )} + \overset{+ 6}{S}{O}_{4}^{2 -} + OH^{-}
'n' factor of Na2S2O3=8N{a}_{2}{S}_{2}{O}_{3} = 8
'n' factor of KMnO4=3KMn{O}_{4} = 3
m.eq of Na2S2O3=N{a}_{2}{S}_{2}{O}_{3} = m.eq of KMnO4KMn{O}_{4}
0.158158×8×1000=0.1×V×3\dfrac{0.158}{158} \times 8 \times 1000 = 0.1 \times \text{V} \times 3
V=26.7mLV = 26.7mL
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