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NTA Abhyas NEET2020ChemistryCarboxylic Acid DerivativesPractice

Consider the following compounds The correct decreasing order of their reactivity towards hydrolysis is

Options

  1. A(i) > (ii) > (iii) > (iv)
  2. B(iv) > (ii) > (i) > (iii)
  3. C(ii) > (iv) > (i) > (iii)
  4. D(ii) > (iv) > (iii) > (i)

Correct answer

C. (ii) > (iv) > (i) > (iii)

Step-by-step solution

The ease of hydrolysis depends upon the magnitude of the +ve charge on the carbonyl group. Electron-withdrawing groups increase the magnitude of positive charge and electron donating groups decrease the magnitude of positive charge. Hence, the decreasing order of reactivity towards hydrolysis is

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