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NEET
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Physics
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Atomic Physics

NEET · Physics · Atomic Physics

A graph is plotted showing the kinetic energy ( K ) of an electron...

A graph is plotted showing the kinetic energy (KK) of an electron on the y-axis versus the reciprocal of its orbital radius (1r\dfrac{1}{r}) on the x-axis. Which of the following statements correctly describes the shape of the graphs and their relative slopes for a Hydrogen atom (H) and a singly ionized Helium ion (He+^+)?

Options

  1. AThe graphs are parabolas, because kinetic energy depends on the square of the velocity.
  2. BThe graphs are straight lines passing through the origin, and the slope for He+^+ is twice the slope for H.
  3. CThe graphs are straight lines passing through the origin, and the slope for He+^+ is four times the slope for H.
  4. DThe graphs are straight lines passing through the origin, and the slope for He+^+ is half the slope for H.

Correct answer

B. The graphs are straight lines passing through the origin, and the slope for He+^+ is twice the slope for H.

Step-by-step solution

The electrostatic force between the nucleus (charge ZeZe) and the electron (charge ee) provides the centripetal force:

mv2r=14πϵ0Ze2r2\dfrac{mv^2}{r} = \dfrac{1}{4\pi\epsilon_0}\dfrac{Ze^2}{r^2}

Multiplying both sides by rr, we get:

mv2=14πϵ0Ze2rmv^2 = \dfrac{1}{4\pi\epsilon_0}\dfrac{Ze^2}{r}

The kinetic energy KK of the electron is:

K=12mv2=18πϵ0Ze2rK = \dfrac{1}{2}mv^2 = \dfrac{1}{8\pi\epsilon_0}\dfrac{Ze^2}{r}

This can be written as:

K=(Ze28πϵ0)×1rK = \left(\dfrac{Ze^2}{8\pi\epsilon_0}\right) \times \dfrac{1}{r}

This is a linear equation of the form y=mxy = mx, where y=Ky = K and x=1rx = \dfrac{1}{r}.

Thus, the graph of KK versus 1r\dfrac{1}{r} is a straight line passing through the origin.

The slope of the graph is m=Ze28πϵ0m = \dfrac{Ze^2}{8\pi\epsilon_0}, which is directly proportional to the atomic number ZZ.

For Hydrogen, Z=1Z = 1. For He+^+, Z=2Z = 2.

Therefore, the slope for He+^+ is exactly twice the slope for H.

Answer: The graphs are straight lines passing through the origin, and the slope for He+^+ is twice the slope for H.
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