NEET2005ChemistryChemical EquilibriumActual
For the chemical equilibrium, CaCO _ 3(s) CaO _ (s) + CO _ 2(g) , H_r^ can be determined from which one of the following plots?
Correct answer
0
Step-by-step solution
For the reaction, K_p=p_ CO ₂ and K_c= [ CO ₂ ] ( [ CaCO ₃ ]=1 . and [ CaO ]=1 for solids ] According to Arrhenius equation we have K=A e^ - H_r^ / R T Taking logarithm, we have K_p= A- H_r^ R T(2.303) This is an equation of straight line. When K_p is plotted against 1 / T . we get a straight line. The intercept of this line = A , slope =- H_r^ / 2.303 R Knowing the value of slope from the plot and universal gas constant R, H_r^ can be calculated. (Equation of straight line : Y=m x+C . Here, aligned & K_p=- H_r^ 2.