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NEET Chemical Equilibrium PYQs with Solutions

448 previous year questions from Chemical Equilibrium (NEET UG Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

448 questionsChemistry2001–2026Answers + solutions

About Chemical Equilibrium PYQs

Chemical Equilibrium has 448 previous year questions in the Quantrex Academy NEET UG Chemistry bank. The 220 questions in this list come from NEET (177), AIIMS (24), JIPMER (18) and 1 other source, spanning 2001 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 2
  • 2025: 2
  • 2024: 5
  • 2022: 2
  • 2019: 1
  • 2018: 8
  • 2017: 3
  • 2016: 1
  • 2015: 5
  • 2014: 5
  • 2013: 3
  • 2012: 5

Chemical Equilibrium questions with solutions

1

For which of the following solids does solubility decrease with an increase in temperature?

MHT CET Medical 2026 Solution
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2

Given below are certain reactions. Identify the reaction for which K_p ≠ K_c :

NEET 2026 Solution
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3

Higher yield of NO in N_2(~g)+O_2(~g) leftharpoons 2 NO(g) can be obtained at [ Δ H of the reaction =+180.7 ~kJ ~mol^ -1 ] A. higher temperature B. lower temperature C. higher

NEET 2025 Solution
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4

For the reaction A(g) leftharpoons 2 ~B(~g) , the backward reaction rate constant is higher than the forward reaction rate constant by a factor of 2500 , at 1000 K . [Given

NEET 2025 Solution
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5

Consider the following reaction in a sealed vessel at equilibrium with concentrations of N_2=3.0 × 10^ -3 M, O_2=4.2 × 10^ -3 M and NO=2.8 × 10^ -3 M . 2 NO_ (g) leftharpoons N_

NEET 2024 Solution
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6

For the reaction 2 ~A leftharpoons B+C, K_ C =4 × 10^ -3 . At a given time, the composition of reaction mixture is: [A]=[B]=[C]=2 × 10^ -3 M . Then, which of the following is

NEET 2024 Solution
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7

For the reaction in equilibrium N_2(~g)+3 H_2(~g) leftharpoons 2 NH_3(~g), Δ H=-Q Reaction is favoured in forward direction by:

NEET 2024 Solution
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8

In which of the following equilibria, K_ p and K_ c are NOT equal?

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9

At a given temperature and pressure, the equilibrium constant values for the equilibria are given below: 3 ~A_2+B_2 leftharpoons 2 ~A_3 ~B, ~K_1 A_3 ~B leftharpoons (3)/(2)

NEET 2024 Solution
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10

K_P for the following reaction is 3.0 at 1000 ~K . CO_2(~g)+C(s) leftharpoons 2 CO(g) What will be the value of K_C for the reaction at the same temperature? (Given: R=0.083 ~L

NEET 2022 Solution
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11

3 O _ 2 ( g ) ⇌ 2 O _ 3 ( g ) for the above reaction at 298K, K _ c is found to be 3 . 0 × 10 ^ - 59 . If the concentration of O _ 2 at equilibrium is 0 . 040M then concentration

NEET 2022 Solution
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12

In which of the following reactions K_p>K_c ?

AIIMS 2019 Solution
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13

A vessel of one litre capacity containing 1 mole of SO_3 is heated till a state of equilibrium is attained. 2 SO_ 3(g) leftharpoons 2 SO_ 2(g) +O_ 2(g) At equilibrium, 0.6 moles

AIIMS 2018 Solution
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14

Assertion : Solubility of gases increases with increase in pressure. Reason : Dissolution of gas in liquid is exothermic.

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15

When pressure is increased at constant temperature

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16

If for the reaction, 2 ICl I_2+Cl_2 ; K_c=0.14 and initial concentration of ICl is 0.6 M then equilibrium concentration of I_2 is

AIIMS 2018 Solution
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17

In the given reaction : A+2 B leftharpoons 2 C 2 moles each of A and B present in 10 ~L of solution combine to form 1 mole of C . Calculate K_c for the reaction.

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18

The value of K_ C for the reaction, 2 ~A leftharpoons B+C is 2 × 10^ -3 . At a given time, the composition of reaction mixture is [A]=[B]=[C]=3 × 10^ -4 M . In which direction

JIPMER 2018 Solution
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19

A chemical reaction was carried out at 300 K and 280 K . The rate constant were found to be k_1 and k_2 respectively, then

JIPMER 2018 Solution
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20

Which one of the following conditions will favor the maximum formation of the product in the reaction? A _ 2 (g) + B _ 2 (g) ⇌ X _ 2 (g) Δ _ r H = - XkJ

NEET 2018 Solution
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21

For the reaction, H_2+I_2 leftharpoons 2 HI, K=47.6 . If the initial number of moles of each reactant and product is 1 mole then at equilibrium

AIIMS 2017 Solution
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22

The equilibrium constants of the following are: cases N _ 2 + 3 H _ 2 ⇌ 2 NH _ 3 & K _ 1 N _ 2 + O _ 2 ⇌ 2NO & K _ 2 H _ 2 + (1)/(2) O _ 2 → H _ 2 O & K _ 3 cases The equilibrium

NEET 2017 Solution
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23

Which one of the following statements is not correct?

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24

Both Mg and Fe metal can reduce copper from a solution having Cu^ 2+ ion, according to equilibria. aligned & Mg_ (s) +Cu^ 2+ leftharpoons Mg^ 2+ +Cu_ (s) ; K_1=6 × 10^ 90 & Fe_

JIPMER 2016 Solution
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25

One mole of SO_3 was placed in a vessel of 1 ~L capacity at a certain temperature and the following equilibrium was established. 2 SO_ 3(g) leftharpoons 2 SO_ 2(g) +O_ 2(g) If 0.6

AIIMS 2015 Solution
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26

For the following equilibrium (omitting charges) I. M+Cl M Cl, K_ eq =β_1 II. M C l+Cl M C l_2, K_ eq =β_2 III. M Cl_2+Cl MCl_3, K_ eq =β_3 IV. M+3 Cl M Cl_3, K_ eq =K then

JIPMER 2015 Solution
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27

aligned & If Ag^ + +2 NH_3 leftharpoons Ag(NH_3)_2^ + ; K_1=1.7 × 10^7 & Ag^ + +Cl^ - leftharpoons AgCl ; K_2=5.4 × 10^9 aligned Then, for AgCl+2 NH_3 leftharpoons[Ag(NH_3)_2]^ +

JIPMER 2015 Solution
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28

If the value of an equilibrium constant for a particular reaction is 1.6 × 10 ^ 12 , then at equilibrium the system will contain:

NEET 2015 Solution
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29

If the equilibrium constant for N _ 2 (g) + O _ 2 ( g ) ⇌ 2NO ( g ) is K, the equilibrium constant for (1)/(2) N _ 2 (g) + (1)/(2) O _ 2 ( g ) ⇌ NO ( g ) will be:

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30

The equilibrium constant for the reaction, (1)/(2) H_ 2(g) +(1)/(2) I_ 2(g) leftharpoons HI_ (g) is K_c . Equilibrium constant for the reaction, 2 HI_ (g) leftharpoons H_ 2(g) +I_

AIIMS 2014 Solution
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31

For the reaction, N_2(~g)+O_2(~g) leftharpoons 2 NO(g) , the equilibrium constant is K_1 . The equilibrium constant is K_2 for the reaction, 2 NO(g)+O_2(~g) leftharpoons 2

JIPMER 2014 Solution
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32

The dissociation equilibrium of a gas A B_2 can be represented as 2 A B_2(g) leftharpoons 2 A B(g)+B_2(g) The degree of dissociation is ' x ' and is small compared to 1 . The

JIPMER 2014 Solution
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33

For the reversible reaction: N _ 2 (g) + 3 H _ 2 (g) ⇌ 2N H _ 3 (g) + heat The equilibrium shifts in forward direction:

NEET 2014 Solution
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34

For a given exothermic reaction K _ p and K' _ p are the equilibrium constants at temperatures T _ 1 and T _ 2 respectively (T 2 .>T 1 ). Assuming that heat of reaction is

NEET 2014 Solution
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35

At equilibrium, the rate of dissolution of a solid solute in a volatile liquid solvent is

JIPMER 2013 Solution
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36

The rate of a gaseous reaction is given by the expression k[A][B] . If the volume of the reaction vessel is suddenly reduced to (1)/(4) th of the initial volume, the reaction rate

JIPMER 2013 Solution
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37

The value of K_c for the reaction, 2 A leftharpoons B+C is 2 × 10^ -3 . At a given time, if the composition of reaction mixture is [A]=[B]=[C]=3 × 10^ -3 M . Which is true?

JIPMER 2013 Solution
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38

At 60^ ∘ and 1 ~atm, ~N_2 O_4 is 50 \% dissociated into NO_2 then K_p is

AIIMS 2012 Solution
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39

(K_p)/(K_c) for following reaction will be

AIIMS 2012 Solution
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40

For the homogeneous reaction, NH_3+OCl^ - N_2 H_4+Cl^ - the equilibrium constant K_c has the units

JIPMER 2012 Solution
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41

Given that the equilibrium constant for the reaction, 2 SO _ 2 (g)+ O _ 2 (g) leftharpoons 2 SO _ 3 (g) has a value of 278 at a particular temperature. What is the value of the

NEET 2012 Solution
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42

Given the reaction between two gases represented by A_2 and B_2 to give the compound A B(g) . A_2(g)+B_2(g) leftharpoons 2 A B(g) At equilibrium, the concentration of A_2=3.0 ×

NEET 2012 Solution
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43

Which of the following is not a characteristic of equilibrium?

AIIMS 2011 Solution
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44

The value of Δ H for the raction X_2(g)+4 Y_2(g)^ 39 2 X Y_4(g) is less than zero. Formation of X Y_4(g) will be favoured at

NEET 2011 Solution
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45

For the reaction, \(N _ 2 ( g)+O _ 2 ( g) leftharpoons 2 NO(g)\), the equilibrium constant is \(K _ 1 \). The equilibrium constant is \( K _ 2 \) for \(2 NO(g)+O _ 2 ( g)

NEET 2011 Solution
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46

Assertion : The equilibrium constant is fixed and a characteristic for any given chemical reaction at a specified temperature. Reason: The composition of the final equilibrium

AIIMS 2010 Solution
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47

In which of the following equilibrium K_C and K_ P are not equal ?

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48

The reaction, \(2 ~A_ (g) +B_ (g) rightharpoons 3 C_ (g) +D_ (g) \) is begun with the concentrations of \(A\) and \(B\) both at an initial value of 1.00 M When equilibrium is

NEET 2010 Solution
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49

A vessel of one litre capacity containing 1 mole of SO_3 is heated till a state of equilibrium is attained. 2 SO_ 3(g) leftharpoons 2 SO_ 2(g) +O_ 2(g) . At equilibrium, 0.6 moles

AIIMS 2009 Solution
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50

The equilibrium constant for mutarotation α -D Glucose leftharpoons β -D Glucose is 1.8 . What percentage of α form remains at equilibrium?

AIIMS 2009 Solution
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51

Assertion : Ice leftharpoons water, if pressure is applied water will evaporate. Reason : Increases of pressure pushes the equilibrium towards the side in which number of gaseous

AIIMS 2009 Solution
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52

In III group precipitation, NH_4 Cl is added before adding NH_4 OH to

JIPMER 2009 Solution
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53

9.2 ~g ~N_2 O_4 is heated in a 1 L vessel till equilibrium state is established N_2 O_4(g) leftharpoons 2 NO_2(g) In equilibrium state 50 \% ~N_2 O_4 was dissociated, equilibrium

JIPMER 2009 Solution
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54

What is the equation for the equilibrium constant (K_c) for the following reaction? (1)/(2) A(g)+(1)/(3) B(g) T(K) leftharpoons (2)/(3) C(g)

JIPMER 2009 Solution
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55

The dissociation constants for acetic acid and HCN at 25^ ∘ C are 1.5 × 10^ -5 and 4.5 × 10^ -10 , respectively. The equilibrium constant for the equilibrium, CN^ - +CH_3 COOH

NEET 2009 Solution
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56

The dissociation equilibrium of a gas \(A B_2\) can be represented as \[ 2 A B_ 2(g) leftharpoons 2 A B_ (g) +B_ 2(g) \] The degree of dissociation is \(x\) and is small compared

AIIMS 2008 Solution
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57

Assertion : According to Le-Chatelier's principle addition of heat to an equilibrium solid \(leftharpoons\) liquid results in decrease in the amount of solid. Reason : Reaction is

AIIMS 2008 Solution
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58

Solubility product of \(PbCl_2\) at 298 K is \(1 × 10^ -6 \). At this temperature solubility of \(PbCl_2\) in \(mol / L\) is

JIPMER 2008 Solution
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59

Bond dissociation enthalpy of H_2, Cl_2 and HCl Enthalpy of formation of HCl is

NEET 2008 Solution
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60

If the concentration of OH^ - ions in the reaction Fe(OH)_3(s) leftharpoons Fe^ 3+ (a q)+3 OH(a q) is decreased by (1)/(4) times, then equilibrium concentration of Fe^ 3+ will

NEET 2008 Solution
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61

If the concentration of OH^ - ions in the reaction Fe(OH)_3(~s) leftharpoons Fe^ 3+ (aq)+3 OH^ - (aq) is decreased by (1)/(4) times, then equilibrium concentration of Fe^ 3+ will

NEET 2008 Solution
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62

The value of equilibrium constant of the reaction HI(g) leftharpoons (1)/(2) H _ 2 ( ~g)+(1)/(2) I _ 2 is 8.0 The equilibrium constant of the reaction H_2(~g)+I_2(~g) leftharpoons

NEET 2008 Solution
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63

The values of K_ P 1 and K_ P 2 for the reactions aligned & X leftharpoons Y+Z . & A leftharpoons 2 B . . aligned are in ratio of 9:1. If degree of dissociation ofX and A be

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64

The dissociation equilibrium of a gas AB_2 can be represented as, 2 AB_2(~g) leftharpoons 2 AB(g)+B_2(~g) . The degree of dissociation is ' x ' and is small compared to 1. The

NEET 2008 Solution
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65

Assertion : The equilibrium constant is fixed and a characteristic for any given chemical reaction at a specified temperature. Reason : The composition of the final equilibrium

AIIMS 2007 Solution
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66

Equilibrium constants K_1 and K_2 for the following equilibria NO(g)+(1)/(2) O_2 K_1 leftharpoons NO_2(g) and 2 NO_2(g) K_2 leftharpoons 2 NO(g)+O_2(g) are related as

JIPMER 2007 Solution
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67

The following equilibrium constant are given: aligned N_2+3 H_2 & leftharpoons 2 NH_3 ; K_1 ~N_2+O_2 & leftharpoons 2 NO ; K_2 H_2+1 / 2 O_2 & leftharpoons H_2 O ; K_3 aligned The

NEET 2007 Solution
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68

A+B leftharpoons C+D . If initially the concentration of A and B are both equal but at equilibrium, concentration of D will be twice of that of A , then what will be the

JIPMER 2006 Solution
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69

For the reaction: CH_ 4(g) +2 O_ 2(g) leftharpoons CO_ 2(g) +2 H_2 O(l) Δ H_r=-170.8 ~kJ ~mol^ -1 . Which of the following statements is not true?

NEET 2006 Solution
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70

For reaction, 2 NOCl_ (g) leftharpoons 2 NO_ (g) +Cl_ 2(g) , K_c at 427^ ∘ C is 3 × 10^ -6 ~L ~mol ^ -1 . The value of K_p is nearly

AIIMS 2005 Solution
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71

For the chemical equilibrium, CaCO_ 3(s) leftharpoons CaO_ (s) +CO_ 2(g) , Δ H_r^ ∘ can be determined from which one of the following plots?

AIIMS 2005 Solution
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72

Equilibrium constants K_1 and K_2 for the following equilibria: are related as:

NEET 2005 Solution
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73

Of the following which change will shift the reaction towards the product? I_ 2(~g) leftharpoons 2 I_ (g) , Δ H_r^ ∘ (298 ~K)=+150 ~kJ

AIIMS 2004 Solution
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74

For the reaction, 2 NO_2 arrow 2 NO+O_2 , the value of K_p is equal to K . What will the value of K_p for reaction, NO+(1)/(2) O_2 NO_2

JIPMER 2004 Solution
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75

The reaction quotient (Q) for the reaction: N_ 2(g) +3 H_ 2(g) leftharpoons 2 NH_ 3(~g) is given by Q= [NH_3]^2 [~N_2][H_2]^3 The reaction will proceed from right to left if:

NEET 2003 Solution
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76

The following equilibrium are given: array ll N_2+3 H_2 leftharpoons 2 NH_3 & ~K_1 ~N_2+O_2 leftharpoons 2 NO & K_2 H_2+(1)/(2) O_2 leftharpoons H_2 O & K_3 array The equilibrium

NEET 2003 Solution
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77

For the reaction BaO_2(s) leftharpoons BaO(s)+O_2(g) ; Δ H=+ve . In an equilibrium condition, pressure of O_2 depends on:

NEET 2002 Solution
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78

In which of the following reaction K_p>K_c ?

AIIMS 2001 Solution
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79

Which of the following is a characteristic of a reversible reaction?

AIIMS 2001 Solution
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80

What is the condition of equilibrium in terms of the rate of opposing processes?

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81

What does it mean when ∆G is equal to 0 for a reaction?

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82

What is the standard state (c 0 ) for a solute when measuring concentrations with respect to it?

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83

What is the term used to describe a mixture of reactants and products in the equilibrium state?

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84

What happens to the rates of forward and reverse reactions at equilibrium?

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85

What does maximum yield of products imply in terms of temperature and pressure conditions?

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86

Which type of reaction involves reactants and products in different phases?

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87

How do molecules escape the liquid surface during evaporation in a closed container?

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88

What is the term used for a chemical reaction that can proceed in both the forward and reverse directions?

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89

How is the concentration expressed in mol/m3 calculated from the ideal gas equation when pressure is in pascals (Pa)?

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90

What happens to the mass of ice and water when they are not in equilibrium?

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91

What happens to the equilibrium when an inert gas like argon is added at constant volume to a reaction?

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92

What determines the concentration of the solute in a saturated solution?

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93

How can a pressure change affect the yield of products in a gaseous reaction?

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94

What characterizes the dynamic nature of chemical equilibrium?

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95

In the context of a reaction with an exceedingly small K, what is the role of a catalyst?

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96

Why does the addition of an inert gas at constant volume not disturb the equilibrium?

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97

How is the extent of a reaction in equilibrium affected by temperature?

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98

What is the state of a chemical reaction when the rates of the forward and reverse reactions become equal?

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99

How does the equilibrium vapor pressure of iodine change with temperature?

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100

What is the primary factor that determines the classification of reactions based on their extent in equilibrium?

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101

How does the temperature affect the equilibrium constant for a given reaction?

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102

According to Le Chatelier's principle, how does a system respond to a change in equilibrium conditions?

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103

In terms of chemical equilibria, what does "net reaction" refer to?

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104

What is the composition of the mixture like when a chemical reaction reaches a state of equilibrium?

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105

How can you relate the equilibrium constant K for a reaction to the equilibrium constant of a related reaction?

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106

What does "homogeneous solution phase" refer to?

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107

What happens at the boundary between ice and water when ice and water are in equilibrium?

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108

When does equilibrium occur in the sublimation of solid iodine?

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109

For the equilibrium 2NOCl(g) ⇌ 2NO(g) + Cl 2 (g), the value of the equilibrium constant, K c is 3.75 × 10–6 at 1069 K. What is the value of K p for the reaction at this

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110

What characteristic of an inert gas makes it not affect the equilibrium?

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111

What commercial application does the removal of a product have in reactions involving gases or volatile substances?

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112

Which law governs the equilibrium between the molecules of a gas and those dissolved in a liquid under pressure?

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113

What gives rise to a constant vapor pressure in a closed container during evaporation?

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114

When is the expression for the equilibrium constant applicable?

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115

What can be calculated using equilibrium constants?

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116

At what stage is the system considered to be in dynamic equilibrium?

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117

What is the significance of using deuterium in the synthesis of ammonia to demonstrate the dynamic nature of equilibrium?

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118

In which direction does the equilibrium shift when a gaseous reaction mixture is compressed to one-half of its original volume?

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119

How does changing the stoichiometric coefficients in a chemical equation affect the equilibrium constant expression?

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120

In a homogeneous system, what is the key characteristic of the phase of reactants and products?

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