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NEET2019Chemistryp Block Elements (Group 13 & 14)Actual

Compound ' X ' on reduction with LiAlH ₄ gives a hydride ' Y ' containing 21.72 % hydrogen along with other products. The compound ' Y ' reacts with air explosively to give B ₂ O ₃ ^ X ' and ' Y ' are respectively

Options

  1. AB ₂ H ₆, BCl ₃
  2. BBCl ₃, ~B ₂ H ₆
  3. CAlCl ₃, AlH ₄⁻
  4. DBCl ₃, ~B ₄ H ₁₀

Correct answer

B. BCl ₃, ~B ₂ H ₆

Step-by-step solution

aligned & 4 BCl ₃+3 LiAlH ₄ Y Ether Y 2 ~B ₂ H ₆ +3 AlCl ₃ & +3 LiCl & % of H in B ₂ H ₆=(6 / 27.62) 100=21.72 & ~B ₂ H ₆+3 O ₂ (air) Explosion B ₂ O ₃+3 H ₂ O & Y & aligned

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