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p Block Elements (Group 13 & 14) — NEET UG Chemistry PYQs

613 previous year questions from p Block Elements (Group 13 & 14) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

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1

Which of the following elements is in allotopic form in fullerene?

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2

Identify the incorrect statement from the following :

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3

In potash alum, the ratio of K ^+ and SO₄²⁻ ions is

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4

Select the element (M) whose trihalides cannot be hydrolysed to produce an ion of the form [ M ( H ₂ O )₆ ]³⁺

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5

Na ₂ ~B ₄ O ₇ heat X + NaBO ₂ in the above reaction the product " X " is :

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6

Match List-I with List-II : ( array l|l List-I & List-II (Compounds) & (Molecular formula) (a) Borax & (i) NaBO ₂ (b) Kernite & (ii) Na ₂ ~B ₄ O ₇ 4 H ₂ O (c) Orthoboric acid & (ii

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7

Which of the following statement is not correct about diborane?

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8

Match the following and identify the correct option. (a) CO g + H 2 g (i) Mg HCO 3 2 + Ca HCO 3 2 (b) Temporary hardness of water (ii) An electron deficient hydride (c) B 2 H 6 (ii

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9

Identify the correct statements from the following: (a) CO 2 g is used as a refrigerant for ice cream and frozen food. (b) The structure of C 60 contains twelve six-membered carbon

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10

Which of the following is not allotrope of carbon?

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11

Which of the following statement is correct for isotope of carbon?

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12

Which of the following compounds is used in cosmetic surgery?

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13

Which one of the following elements is unable to form MF 6 3 - ion?

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14

In the reaction X+ I ₂+2 HCl SnCl ₄+2 HI The correct option regarding X is/are

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15

Boric acid is an acid because its molecule

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16

AlF 3 is soluble in HF only in presence of KF . It is due to the formation of

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17

Number of oxygen atoms shared per SiO ₄⁴⁻ tetrahedron in I. two dimensional sheet structured silicates II. cyclic silicates and III. single strand chain silicates respectively are

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18

The stability of +1 oxidation state among Al, Ga, In and Tl increases in the sequence:

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19

Which one of the following statements about C ₂ molecule is wrong?

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20

Which statement is wrong?

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21

The basic structural unit of silicates is

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22

Which of these is not a monomer for a high molecular mass silicone polymer?

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23

Which of the following is electron deficient?

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24

Which of the following statements is incorrect?

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25

Name the type of the structure of silicate in which one oxygen atom of [ SiO ₄ ]⁴⁻ is shared?

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26

Inorganic benzene is

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27

The tendency of BF ₃, BCl ₃ and BBr ₃ to behave as Lewis acid decreases in the sequence

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28

The straight chain polymer is formed by

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29

With which one of the following elements silicon should be doped so as to give ptype of semiconductor?

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30

Which of the following is the electron deficient molecule?

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31

Which of the following oxidation states are the most characteristics for lead and tin respectively?

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32

Which of the following anions is present in the chain structure of silicates?

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33

Which of the following compounds is carborundum?

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34

Which of the following is the most basic oxide?

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35

Al ₂ O ₃ can be converted to anhydrous AlCl ₃ by heating:

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36

The hardest substance is

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37

Graphite is soft while diamond is hard because

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38

Which of the following is the electron deficient molecule?

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39

Which one of the following statements about the zeolite is false?

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40

What property of gallium makes it a useful material for measuring high temperatures?

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41

What are some products that use graphite fibers embedded in plastic composites?

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42

Which compound is used as a reducing agent in organic synthesis and is derived from diborane?

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43

What type of compounds do amorphous boron and aluminum form when heated in air?

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44

What is the basic structural unit of silicates?

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45

What are some of the characteristics of aluminum?

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46

Which two elements have a noble gas core in their electronic configuration?

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47

What type of compounds do highly reactive non-metals form with highly reactive metals?

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48

What does orthoboric acid form when heated above 370K?

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49

Why is diamond considered the hardest substance on Earth?

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50

What is the color of diborane?

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51

What is the unit of measurement for diamond?

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52

Why is lead unaffected by water?

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53

What is expected to happen to the atomic radius as you move down the group?

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54

What is the trend in ionization enthalpy values expected as you move down the group?

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55

What are water gas and producer gas primarily used for in industrial applications?

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56

Why can most tetrachlorides be easily hydrolyzed by water?

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57

What is the nature of the oxides of aluminum and gallium?

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58

What is the stable isotope of naturally occuring carbon?

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59

What is the role of copper in the synthesis of silicones?

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60

What causes the observed discontinuity in ionization enthalpy values between aluminum and gallium?

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61

What are some of the applications of silicones?

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62

What property of graphite makes it suitable for making crucibles?

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63

What is the nature of non-metal oxides?

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64

Which elements are members of group 14?

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65

What is the general electronic configuration of the first member of Group 13 in the periodic table?

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66

What is the energy change (Δ) associated with the combustion of diborane in oxygen?

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67

Why are silicones water-repelling in nature?

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68

How would you describe the melting points and boiling points of group 14 elements compared to those of corresponding elements in group 13?

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69

What is the melting point of gallium?

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70

How many d-electrons are present in the electronic configuration of gallium and indium?

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71

How many isotopic forms of boron are there?

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72

Why does boron primarily form covalent compounds?

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73

What is the maximum oxidation state shown by a p-block element?

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74

Which minerals are mentioned as important sources of aluminum?

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75

What tendency do group 14 elements have in forming complexes with donor species?

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76

What is the distance between two layers of graphite?

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77

What property of carbon monoxide (CO) makes it useful in the extraction of metals from their oxide ores?

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78

What does the oxide layer on the surface of aluminum do?

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79

What is the glass-like material obtained when borax further heats up and solidifies?

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80

Among the heavier members of group 14, which element shows the highest tendency to exhibit a +2 oxidation state?

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81

Are oxides in higher oxidation states generally more acidic or basic than those in lower oxidation states?

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82

What gives aromatic character to the C60 molecule?

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83

What are two important man-made silicates?

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84

How many vertices does a Buckminsterfullerene (C60) molecule have, and what occupies each vertex?

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85

What is the main industrial application of borax and boric acid?

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86

Which element has the atomic number 113?

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87

What is quartz extensively used for?

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88

How is pure carbon monoxide (CO) prepared on a small scale?

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89

What is the behavior of the halides of group 14 elements in terms of hydrolysis?

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90

What is the temperature at which the reaction between methyl chloride and silicon takes place?

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91

How does concentrated nitric acid affect aluminum?

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92

How can silicate units be joined together in silicate structures?

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93

What is the seventeenth most abundant element by mass in the earth's crust?

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94

How does the ionization enthalpy generally change as you move down group 14?

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95

What happens to the overall structure of silicon dioxide when aluminum atoms replace some silicon atoms?

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96

How is carbon black obtained?

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97

In what forms is carbon available in its elemental state?

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98

What is the primary reason for the higher electronegativity of group 14 elements?

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99

Under what conditions does SiO exist?

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100

What property of graphite makes it conduct electricity?

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101

What are the two main types of oxides formed by all members when heated in oxygen?

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102

Which substances attack silica?

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103

What is the bond length within each layer of graphite?

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104

What are some of the industries where aluminum and its alloys find uses?

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105

What effect does the sum of the first three ionization enthalpies have on the chemical properties of these elements?

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106

Which element in the group 13 is known to exhibit both +1 and +3 oxidation states?

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107

Which element is the exception and does not form trihalides?

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108

What is the thermodynamically most stable allotrope of carbon?

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109

Which group 13 element lacks d orbitals, limiting its covalence to 4?

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110

What is kieselghur?

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111

What is the product obtained when metaboric acid is further heated?

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112

Which two elements in group 14 are "soft metals with low melting points"?

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113

What is the maximum covalence for the second period elements of p-groups?

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114

What are the composites made from graphite fibers and plastic used in?

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115

What is the nature of the oxides of indium and thallium?

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116

How does the metal species complete its octet in halogen-bridged molecules?

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117

Which elements head the groups in the p-block of the periodic table?

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118

Why does boron have an unusually high melting point?

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119

How many sigma and pi bonds are present between carbon and oxygen in a carbon monoxide (CO) molecule?

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120

How does the tendency to behave as Lewis acids change as you move down the group?

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