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NEET2007Chemistryp Block Elements (Group 13 & 14)Actual

Which of the following is the electron deficient molecule?

Options

  1. AB ₂ H ₆
  2. BC ₂ H ₆
  3. CPH ₃
  4. DSiH ₄

Correct answer

A. B ₂ H ₆

Step-by-step solution

B ₂ H ₆ is electron deficient molecule because boron atom has three half filled orbitals in excited state. The structure of B ₂ H ₆ is represented as follows: In it two electrons of a B - H bond are involved in formation of three centre bond, these bonds are represented as dotted lines.

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