NEETChemistryHydrocarbons
What is the name of the addition reaction that takes place contrary to the Markovnikov rule in the presence of peroxide when HBr is added to unsymmetrical alkenes like propene?
Options
- AKharash reaction
- BMarkovnikov addition
- CRadical halogenation
- DPeroxide effect
Correct answer
A. Kharash reaction
Step-by-step solution
The addition reaction that occurs contrary to the Markovnikov rule in the presence of peroxide when HBr is added to unsymmetrical alkenes is known as the Kharash reaction.