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NEET Hydrocarbons PYQs with Solutions

757 previous year questions from Hydrocarbons (NEET UG Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

757 questionsChemistry2002–2026Answers + solutions

About Hydrocarbons PYQs

Hydrocarbons has 757 previous year questions in the Quantrex Academy NEET UG Chemistry bank. The 220 questions in this list come from NEET (172), JIPMER (29) and MHT CET Medical (19), spanning 2002 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 26
  • 2025: 2
  • 2024: 3
  • 2023: 1
  • 2021: 4
  • 2020: 4
  • 2019: 7
  • 2018: 2
  • 2017: 4
  • 2016: 8
  • 2015: 8
  • 2014: 2

Hydrocarbons questions with solutions

1

H_3C-CH=CH_2 + H-Br (C_6H_5CO)_2O_2,\ Benzoyl peroxide H_3C-CH_2-CH_2-Br Which of the following rules is followed when the above reaction occurs?

MHT CET Medical 2026 Solution
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2

Which of the following reagent is NOT required for the conversion of propyne to acetone?

MHT CET Medical 2026 Solution
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3

Palladised charcoal with quinoline is known as

MHT CET Medical 2026 Solution
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4

Chlorination of alkane is a photochemical process. It is initiated by the process of

MHT CET Medical 2026 Solution
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5

Identify A and B in above reaction.

MHT CET Medical 2026 Solution
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6

Chlorobenzene is formed by the reaction between benzene and chlorine in presence of AlCl_3 . Which of the following species actually attacks the benzene ring in this reaction?

MHT CET Medical 2026 Solution
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7

Identify the product obtained when toluene reacts with chlorine in the presence of FeCl_3 .

MHT CET Medical 2026 Solution
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8

In the combustion reaction of alkanes, if 1 mole of ethane is burnt, find number of moles of oxygen required?

MHT CET Medical 2026 Solution
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9

Chlorobenzene on reaction with acetyl chloride in presence of anhydrous aluminum chloride forms,

MHT CET Medical 2026 Solution
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10

What is the major product obtained by oxidation of phenylethene with KMnO_4 in dilute H_2SO_4 ?

MHT CET Medical 2026 Solution
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11

Identify the products when benzene reacts with chlorine in the presence of (I) Fe and (II) anhydrous AlCl_3 respectively from the following.

MHT CET Medical 2026 Solution
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12

Identify the type of reaction when benzene reacts with nitrating mixture.

MHT CET Medical 2026 Solution
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13

Which of the following gases is evolved as a byproduct (A) in the following reaction, HC + LiNH_2 solvent HC=C^-Li^+ + (A)

MHT CET Medical 2026 Solution
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14

Which of the following alkenes forms formaldehyde and acetaldehyde on ozonolysis?

MHT CET Medical 2026 Solution
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15

Aldehydes and Ketones can be converted to alkanes using (A). LiAlH_4 / H_3 O^+ (B). Zn-Hg/ conc^n HCl (C). NH_2 -NH_2 / KOH in ethylene glycol (D). K_2 Cr_2 O_7 / dil.H_2 SO_4

MHT CET Medical 2026 Solution
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16

Identify the major product of the reaction between propene and HBr in the presence of peroxide.

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17

Which one of the following alkenes forms the same product with HBr in the absence as well as in the presence of peroxide?

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18

What is the general molecular formula for alkenes?

MHT CET Medical 2026 Solution
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19

Which of the following types exhibits 100\% atom economy?

MHT CET Medical 2026 Solution
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20

Consider the following reaction, and choose the correct option.

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21

Given below are two statements: Statement I: trans -But-2-ene upon treatment with Br _2 in CCl _4 gives the following product Statement II: cis -But-2-ene upon treatment with

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22

Among the following, the compound having conjugated double bonds is

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23

For the following reaction sequence, choose the correct option

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24

Two products X and Y are formed in the following reaction sequence. C_6H_6 + CH_3Cl Anhydr. AlCl_3 W [warm] dil. HNO_3 + dil. H_2SO_4 X + Y The suitable method that can be used

NEET 2026 Solution
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25

The number of chlorine atoms present in the organic products X and Y of the following reactions, respectively, are : C_6H_6 + 6Cl_2 [dark, cold] Anhydr. AlCl_3 X C_6H_6 + 3Cl_2

NEET 2026 Solution
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26

Consider the following reaction sequences and choose the correct option.

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27

Which one of the following compounds does not decolourize bromine water?

NEET 2025 Solution
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28

Which one of the following reactions does NOT give benzene as the product?

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29

The major product X formed in the following reaction sequence is:

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30

The alkane that can be oxidized to the corresponding alcohol by KMnO_4 as per the equation is, when:

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31

Identify the correct reagents that would bring about the following transformation.

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32

The correct order for the rate of α, β -dehydrohalogenation for the following compounds is

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33

The major product of the following chemical reaction is:

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34

The major product formed in the dehydrohalogenation reaction of 2 -Bromopentane is Pent 2 -ene. This product formation is based on?

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35

The intermediate compound ' X ' in the following chemical reaction is:

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36

Reagent R will be:

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37

Which of the following is a free radical substitution reaction?

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38

Elimination reaction of 2 -Bromo-pentane to form pent- 2 -ene is (a) β -Elimination reaction (b) Follows Zaitsev rule (c) Dehydrohalogenation reaction (d) Dehydration reaction

NEET 2020 Solution
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39

Which of the following alkane cannot be made in good yield by Wurtz reaction?

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40

An alkene on ozonolysis gives methanal as one of the product. Its structure is

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41

Glucose HCN X Hydrolysis Y Red P+HI Z IUPAC name of Y and Z

JIPMER 2019 Solution
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42

CH ≡ CH [H_2 O] Hg^ 2+ / H^ + A LiAlH_4 ~B P / Br_2 C final product C is

JIPMER 2019 Solution
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43

If react with Cl_2 in presence of light and then react with Na metal in dry ether, final product is

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44

The alkane that gives only one mono-chloro product on chlorination with Cl_2 in presence of diffused sunlight is

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45

The most suitable reagent for the following conversion, is:

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46

In the following reaction, the number of sigma( σ ) bonds present in the product A is

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47

An alkene ' A ' on reaction with O _ 3 and Zn - H _ 2 O gives propanone and ethanal in equimolar ratio. Additional of HCl to alkene ' A ' gives ' B ' as the major product. The

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48

Identify the major products P, Q and R in the following sequence of reactions:

NEET 2018 Solution
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49

Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to gaseous hydrocarbon containing less than four carbon atoms.

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50

Which of the following is the major product in the reaction of HOBr with propene?

JIPMER 2017 Solution
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51

1-butyne on oxidation with hot alkaline KMnO_4 would yield. Which of the following as end product?

JIPMER 2017 Solution
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52

Clemmensen reaction of ketone is carried out in the presence of

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53

Which among the following depicts the correct order of acidity?

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54

In the reaction, How many electron donating groups are attached with the carbon atom of unsaturated part of the product ' B ' ?

JIPMER 2016 Solution
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55

Which of the following hydrocarbons is the most reactive towards addition of H_2 SO_4 ?

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56

Which of the following compounds shall not produce propene by reaction with HBr followed by elimination or direct only elimination reaction?

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57

In the reaction X and Y are:

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58

For the following reactions: a. CH _ 3 CH _ 2 CH _ 2 Br + KOH → CH _ 3 CH = CH _ 2 + KBr + H _ 2 O b. c. Which of the following statements is correct?

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59

The compound that will react most readily with gaseous bromine has the formula:

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60

In the given reaction, the product P is

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61

Consider the nitration of benzene using mixed conc. H _ 2 S O _ 4 and HN O _ 3 . If a large amount of KHS O _ 4 is added to the mixture, the rate of nitration will be:

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62

Δ H and Δ S for the reaction, Ag_2 O(s) 2 Ag(s)+(1)/(2) O_2(~g) , are 30.56 ~kJ ~mol^ -1 and 66.00 JK^ -1 ~mol^ -1 respectively. The temperature at which the free energy change

JIPMER 2015 Solution
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63

Find out the correct stereoisomeric product for the following reaction,

JIPMER 2015 Solution
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64

X, Y and Z respectively are

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65

In the reaction with HCl , an alkene reacts following the Markovnikov's rule to give the product 1 - chloro - 1 - methylcyclohexane. The possible reaction of the alkene is

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66

2,3-Dimethyl-2-butene can be prepared by heating which of the following compounds with a strong acid?

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67

The oxidation of benzene by V _ 2 O _ 5 in the presence of air produces:

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68

The reaction of C _ 6 H _ 5 CH = CHC H _ 3 with HBr produces:

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69

Given, The enthalpy of hydrogenation of these compounds will be in the order as:

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70

Which one of the following is aromatic?

JIPMER 2014 Solution
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71

Identify Z in the sequence of reactions:

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72

Addition of water to alkynes occurs in acidic medium and in the presence of Hg^ 2+ ions as a catalyst. Which of the following products will be formed on addition of water to

JIPMER 2013 Solution
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73

Identify the major product ' X ' obtained in the following reaction. 2, 3-dimethyl butan -2- ol Conc. H_2 SO_4 X

JIPMER 2013 Solution
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74

Phenol is distilled with Zn dust followed by Friedel-Crafts alkylation with propyl chloride in the presence of AlCl_3 to give a compound (b). (b) is oxidised in the presence of

NEET 2013 Solution
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75

The structure of isobutyl group in an organic compound is

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76

Nitrobenzene on reaction with conc. HNO_3 / H_2 SO_4 at 80-100^ ∘ C forms which one of the following products?

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77

In the reaction, A is

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78

Which of the following compounds will not undergo Friedal-Craft's reaction easily?

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79

Which one of these is not true for benzene?

JIPMER 2012 Solution
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80

Petrol for aviation purpose must contain

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81

Propyne on passing through red hot copper tube forms

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82

In the following reaction,

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83

Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne?

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84

Clemmensen reduction of a ketone is carried out in the presence of which of the following?

NEET 2011 Solution
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85

CaC_2 and H_2 O react to produce

JIPMER 2010 Solution
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86

The only o p-directing group which is deactivating in nature is

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87

Liquid hydrocarbons can be converted to a mixture of gaseous hydrocarbons by

NEET 2010 Solution
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88

The homologue of ethyne is

JIPMER 2009 Solution
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89

Nitrobenzene can be prepared from benzene by using a mixutre of conc HNO_3 and conc. H_2 SO_4 . In the mixture, nitric acid acts as a/an :

NEET 2009 Solution
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90

Benzene reacts with CH_3 Cl in the presence of anhydrous AlCl_3 to form

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91

Consider the following reaction The product Z is :

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92

Benzene reacts with CH_3 Cl in the presence of anhydrous AlCl_3 to form -

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93

Standard free energies of formation (in kJ / mol ) at 298 ~K are -237.2,-394.4 and -8.2 for H_2 O(l) CO_2(g) and pentane (g) , respectively. The value of E_ cell ^0 for the

NEET 2008 Solution
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94

The relative reactivities of acyl compounds towards nucleophilic substitution are in the order of

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95

A (predominantly) is

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96

Which one the following is most reactive towards electrophilic attack?

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97

Which one of the following alkenes will react faster with H_2 under catalytic hydrogenation conditions? ( R= Alkyl substituent )

JIPMER 2007 Solution
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98

Products of the following reaction CH_3 C ≡ C - CH_2 CH_3 [(2) Hydrolysis ] (1) O_3 … are

JIPMER 2007 Solution
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99

Electrolytic reduction of nitrobenzene in weakly acidic medium gives

JIPMER 2007 Solution
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100

Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is called:

NEET 2007 Solution
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101

The order of decreasing reactivity towards an electrophilic reagent, for the following would be: (i) benzene (ii) toluene (iii) chlorobenzene (iv) phenol

NEET 2007 Solution
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102

Predict the product C obtained in the following reaction of butyne- 1 : CH_3 CH_2-C ≡ CH+HCl arrow B HI C

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103

Which of the compounds with molecular formula C_5 H_ 10 yields acetone on ozonolysis?

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104

By which one of the following compounds both CH_4 and CH_3-CH_3 can be prepared in one step ?

JIPMER 2006 Solution
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105

The reaction of HBr with in the presence of peroxide will give :

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106

reacts with acetic acid in presence of Hg^ 2+ to give:

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107

Butyne-1 and butyne- 2 can be distinguished by

JIPMER 2005 Solution
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108

Which one of the following alkenes will react faster with H_2 under catalytic hydrogenation conditions?

NEET 2005 Solution
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109

Product of the following reaction: CH_3 C ≡ CH_2 CH_3 (ii) hydrolysis (i) O_3 are

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110

Which one of the following compounds is most acidic?

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111

What is obtained, when potassium succinate soluton is electrolysed?

JIPMER 2004 Solution
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112

What is 'X' in the following sequence? Ar. N_2 Cl [KCN] CuCN Z H . OH Y [Δ] soda-lime X

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113

Reaction of HBr with propene in the presence of peroxide gives:

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114

Which of the following is least reactive in a nucleophilic substitution reaction?

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115

Using anhydrous AlCl_3 as catalyst, which one of the following reactions produces ethylbenzene (PhEt) ?

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116

Which one of the following is a free radical substitution reaction?

NEET 2003 Solution
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117

The compound on reaction with NaIO_3 in the present of KMnO_4 gives:

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118

The correct order of reactivity towards the electrophillic substitution of the compounds aniline (I), benzene (II) and nitrobenzene (III) is:

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119

When CH_3 CH_2 CHCl_2 is treated with NaNH_2 , the product formed is:

NEET 2002 Solution
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120

Which of the following compounds is commonly used as a solvent in the Friedel-Crafts alkylation reaction?

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