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MHT CET 202624 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
24 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Hydrocarbons

MHT CET 2026 · 24 April · Morning Shift · Chemistry · Hydrocarbons

Chlorobenzene is formed by the reaction between benzene and...

Chlorobenzene is formed by the reaction between benzene and chlorine in presence of AlCl3\text{AlCl}_3. Which of the following species actually attacks the benzene ring in this reaction?

Options

  1. ACl−\text{Cl}^-
  2. BCl2\text{Cl}_2
  3. CCl+\text{Cl}^+
  4. DAlCl4−\text{AlCl}_4^-

Correct answer

C. Cl+\text{Cl}^+

Step-by-step solution

The reaction of benzene with chlorine in the presence of AlCl3\text{AlCl}_3 is an electrophilic aromatic substitution.

The Lewis acid AlCl3\text{AlCl}_3 reacts with Cl2\text{Cl}_2 to generate the chloronium ion, Cl+\text{Cl}^+, which acts as an electrophile.

Cl2+AlCl3→Cl++AlCl4−\text{Cl}_2 + \text{AlCl}_3 \rightarrow \text{Cl}^+ + \text{AlCl}_4^-

The electrophile Cl+\text{Cl}^+ then attacks the electron-rich benzene ring to form a resonance-stabilized carbocation (sigma complex).

Thus, the species that actually attacks the benzene ring is Cl+\text{Cl}^+.

Answer: Cl+\text{Cl}^+
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