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MHT CET 202625 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
25 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Hydrocarbons

MHT CET 2026 · 25 April · Evening Shift · Chemistry · Hydrocarbons

Identify A and B in above reaction.

Identify A and B in above reaction.
Identify A and B in above reaction.

Options

  1. AIn Bohr's orbit, (n h)/(2 π) indicates
  2. BIn Bohr's orbit, (n h)/(2 π) indicates
  3. CIn Bohr's orbit, (n h)/(2 π) indicates
  4. DIn Bohr's orbit, (n h)/(2 π) indicates

Correct answer

A. In Bohr's orbit, (n h)/(2 π) indicates

Step-by-step solution

The starting material is a cyclohexene derivative with a methoxy group (−OCH3-\text{OCH}_3) at C1, a double bond between C2 and C3, and a nitro group (−NO2-\text{NO}_2) at C4.

In the first step, electrophilic addition of HCl\text{HCl} to the double bond occurs. Protonation of the C2=C3\text{C2}=\text{C3} double bond can form a carbocation at either C2 or C3.
A carbocation at C3 is adjacent to the −NO2-\text{NO}_2 group, which is strongly electron-withdrawing via its −I-I effect, making this intermediate highly unstable.
A carbocation at C2 is adjacent to the −OCH3-\text{OCH}_3 group. Although −OCH3-\text{OCH}_3 also exerts a −I-I effect, it is significantly weaker than that of −NO2-\text{NO}_2. Thus, the intermediate carbocation predominantly forms at C2.

The chloride ion (Cl−\text{Cl}^{-}) then attacks the more stable carbocation at C2. Therefore, the major product [A] is the 2-chloro isomer.

In the second step, [A] reacts with NaI\text{NaI} in dry acetone. This is a standard Finkelstein reaction, which proceeds via an SN2S_N2 mechanism to substitute the chlorine atom with an iodine atom.
The replacement occurs at the same carbon (C2), yielding the 2-iodo isomer as the major product [B].

Comparing this with the given options, Option (1) correctly shows [A] with the −Cl-\text{Cl} group at C2 and [B] with the −I-\text{I} group at C2.

Answer:
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