MHT CET 202625 AprilEvening Shift
- Exam
- MHT CET
- Year
- 2026
- Date
- 25 April
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Hydrocarbons
MHT CET 2026 · 25 April · Evening Shift · Chemistry · Hydrocarbons
Identify A and B in above reaction.
Identify A and B in above reaction.


Options
- A

- B

- C

- D

Correct answer
A. 
Step-by-step solution
The starting material is a cyclohexene derivative with a methoxy group () at C1, a double bond between C2 and C3, and a nitro group () at C4.
In the first step, electrophilic addition of to the double bond occurs. Protonation of the double bond can form a carbocation at either C2 or C3.
A carbocation at C3 is adjacent to the group, which is strongly electron-withdrawing via its effect, making this intermediate highly unstable.
A carbocation at C2 is adjacent to the group. Although also exerts a effect, it is significantly weaker than that of . Thus, the intermediate carbocation predominantly forms at C2.
The chloride ion () then attacks the more stable carbocation at C2. Therefore, the major product [A] is the 2-chloro isomer.
In the second step, [A] reacts with in dry acetone. This is a standard Finkelstein reaction, which proceeds via an mechanism to substitute the chlorine atom with an iodine atom.
The replacement occurs at the same carbon (C2), yielding the 2-iodo isomer as the major product [B].
Comparing this with the given options, Option (1) correctly shows [A] with the group at C2 and [B] with the group at C2.
Answer:
In the first step, electrophilic addition of to the double bond occurs. Protonation of the double bond can form a carbocation at either C2 or C3.
A carbocation at C3 is adjacent to the group, which is strongly electron-withdrawing via its effect, making this intermediate highly unstable.
A carbocation at C2 is adjacent to the group. Although also exerts a effect, it is significantly weaker than that of . Thus, the intermediate carbocation predominantly forms at C2.
The chloride ion () then attacks the more stable carbocation at C2. Therefore, the major product [A] is the 2-chloro isomer.
In the second step, [A] reacts with in dry acetone. This is a standard Finkelstein reaction, which proceeds via an mechanism to substitute the chlorine atom with an iodine atom.
The replacement occurs at the same carbon (C2), yielding the 2-iodo isomer as the major product [B].
Comparing this with the given options, Option (1) correctly shows [A] with the group at C2 and [B] with the group at C2.
Answer: