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In the peroxide effect, why is 1-bromopropane formed as the major product when HBr is added to propene?

Options

  1. AFormation of a primary free radical
  2. BFormation of a secondary free radical
  3. CFormation of a tertiary free radical
  4. DFormation of a quaternary free radical

Correct answer

B. Formation of a secondary free radical

Step-by-step solution

In the peroxide effect, 1-bromopropane is formed as the major product because the secondary free radical formed in the mechanism is more stable than a primary free radical.

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