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NEETChemistryHydrocarbons

Benzene reacts with carbon monoxide and hydrogen chloride in the presence of anhydrous aluminum chloride and cuprous chloride to form compound X . When compound X is heated with concentrated sodium hydroxide, it yields two compounds, Y and Z . The compounds Y and Z are respectively:

Options

  1. ASodium phenoxide and water
  2. BSodium benzoate and water
  3. CSodium benzoate and benzyl alcohol
  4. DBenzyl alcohol and sodium formate

Correct answer

C. Sodium benzoate and benzyl alcohol

Step-by-step solution

The reaction of benzene with carbon monoxide ( CO ) and hydrogen chloride ( HCl ) in the presence of anhydrous AlCl ₃ and CuCl is the Gattermann-Koch reaction. The product X formed is benzaldehyde ( C ₆ H ₅ CHO ). Benzaldehyde does not contain any -hydrogen atoms. When heated with a concentrated alkali like concentrated NaOH , aldehydes lacking -hydrogens undergo the Cannizzaro reaction. This is a disproportionation reaction where one molecule of the aldehyde is reduced to the corresponding alcohol and another is o

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