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AIIMS2012ChemistryThermodynamics (C)

Bond dissociation energy of CH ₄ is 360 ~kJ / mol and C ₂ H ₆ is 620 ~kJ / mol . Then bond dissociation energy of C - C bond is

Options

  1. A170 ~kJ / mol
  2. B50 ~kJ / mol
  3. C80 ~kJ / mol
  4. D220 ~kJ / mol

Correct answer

C. 80 ~kJ / mol

Step-by-step solution

Dissociation energy of methane =360 ~kJ ~mol ⁻¹ Bond energy of C - H bond = 360 4 =90 ~kJ Bond energy of ethane, 1( C - C )+6( C - H )=620 ~kJ / mol (C-C)+6 90=620(C-C)+540=620C-C=620-540 C - C =80 ~kJ ~mol ⁻¹ Bond dissociation of C - C bond =80 ~kJ ~mol ⁻¹ .

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