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NEET2012ChemistryElectrochemistryActual

Standard reduction potentials of the half reactions are given below array ll F ₂(g)+2 e⁻ 2 ~F ⁻(a q) ; & E^ =+2.85 ~V Cl ₂(g)+2 e⁻ 2 Cl ⁻(a q) ; & E^ =+1.36 ~V Br ₂(l)+2 e⁻ 2 Br ⁻(a q) ; & E^ =+1.06 ~V I ₂(s)+2 e⁻ 2 I ⁻(a q) ; & E^ =+0.53 ~V array The strongest oxidising and reducing agents respectively are

Options

  1. AF ₂ and I ⁻
  2. BBr ₂ and Cl ⁻
  3. CCl ₂ and Br ⁻
  4. DCl ₂ and I ₂

Correct answer

A. F ₂ and I ⁻

Step-by-step solution

Higher the value of standard reduction potential, stronger will be the oxidising agent. Therefore, F ₂ will act as strongest oxidising agent. Similarly lower the value of standard reduction potential, stronger will be the reducing agent. Therefore, I ⁻ will act as strongest reducing agent.

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