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NEET
Exam
NEET
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

NEET · Chemistry · Haloalkanes and Haloarenes

Assertion (A) S_N 1 hydrolysis of optically active 2- bromooctane...

Assertion (A) SN1S_N 1 hydrolysis of optically active 2- bromooctane results in the formation of ((\pm)) - octan -2-ol. Reason ((\mathrm{R})) The reation proceeds through a planar carbocation which can be attacked by the nucleophile from either side. The correct answer isAssertion (A) S_N 1 hydrolysis of optically active 2- bromooctane results in the formation of ((±)) - octan -2-ol.

Options

  1. A(A) and (R) are correct, (R) is the correct explanation of ((\mathrm{A}))
  2. B(A) and ((\mathrm{R})) are correct but ((\mathrm{R})) is not the correct explanation of ((\mathrm{A}))
  3. C(A) is correct but (R)(R) is not correct
  4. D(A)(A) is not correct but (R)(R) is correct

Correct answer

A. (A) and (R) are correct, (R) is the correct explanation of ((\mathrm{A}))

Step-by-step solution

Given, Assertion, (A) and the Reason (R), both are correct and the given Reason (R) is the correct explanation of the given (A). Because (S_{\mathrm{N}} 1) reactions occurs through the formation of carbocation. And in (S_{\mathrm{N}} 1) reaction both front as well rear attack of nucleophile at carbocation are possible. In 2-bromooctane, following carbocation is formed. Assertion (A) S_N 1 hydrolysis of optically active 2- bromooctane results in the formation of ((±)) - octan -2-ol.
Thus, option (a) is the correct answer.
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