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NEET
Exam
NEET
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

NEET · Chemistry · Haloalkanes and Haloarenes

Which of the following statements are correct? A. The C-Cl bond in...

Which of the following statements are correct? A. The C−Cl\mathrm{C}-\mathrm{Cl} bond in chlorobenzene is shorter than in chloromethane. B. It is difficult to replace chlorine from chlorobenzene than from benzyl chloride. C. The C−Cl\mathrm{C}-\mathrm{Cl} bond in chlorobenzene has some double bond character. D. Chlorobenzene on chlorination gives m-dichlorobenzeneWhich of the following statements are correct? A. The C-Cl bond in chlorobenzene is shorter than in chloromethane. B.

Options

  1. AA, B, C
  2. BA, D only
  3. CB, C, D
  4. DC, D only

Correct answer

A. A, B, C

Step-by-step solution

Which of the following statements are correct? A. The C-Cl bond in chlorobenzene is shorter than in chloromethane. B.
Chlorobenzene has double bond character between C\mathrm{C} and Cl\mathrm{Cl}. So, it is difficult to replace form than form benzyl chloride. (c) C−Cl\mathrm{C}-\mathrm{Cl} has double bond character in chlorobenzene. (d) Chlorobenzene on chlorination gives mm-dichlorobenzene due to o/po / p-directing effect of Cl\mathrm{Cl}. Thus, option (a) is correct.
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