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NEET
Exam
NEET
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

NEET · Chemistry · Haloalkanes and Haloarenes

Which of the following gives cyanide when reacted with KCN (A)...

Which of the following gives cyanide when reacted with KCN (A) Chloro benzene (B) Allyl bromide (C) Vinyl chloride (D) Benzyl bromide

Options

  1. AA, B and C are correct
  2. BA and B are correct
  3. CB and D are correct
  4. DA and C are correct

Correct answer

C. B and D are correct

Step-by-step solution

The reaction with KCN (potassium cyanide) involves an SN1 or SN2 nucleophilic substitution, where the cyanide ion (CN-) replaces a leaving group. (B) Allyl bromide ((CH\mathrm{CH}2=CH−CH\mathrm{CH}-\mathrm{CH}2 Br)\mathrm{Br})) and (D) Benzyl bromide ((C\mathrm{C}6 H\mathrm{H}5-CH\mathrm{CH}2 Br)\mathrm{Br})) both undergo SN1 or SN2 reactions with KCN to form the corresponding cyanides: - Allyl bromide →→ Allyl cyanide ((CH\mathrm{CH}2=CH−CH\mathrm{CH}-\mathrm{CH}2 CN\mathrm{CN})) - Benzyl bromide →→ Benzyl cyanide (C6H5-CH2CN) (A) Chlorobenzene (C6H5Cl) does not react with KCN because the Cl - is not a good leaving group in an aromatic ring. (C) Vinyl chloride ((CH\mathrm{CH}2=CHCl)\mathrm{CHCl})) does not undergo SN 1 or SN 2 reactions with KCN due to the stability of the vinyl carbocation and the presence of a chlorine atom bonded to a double bond, making it less reactive. Therefore, only Allyl bromide and Benzyl bromide react with KCN to give cyanide compounds. Hence, option (3) is correct.
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