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NEETChemistryHaloalkanes and Haloarenes

Match List- I with List- II . array ll List-l: Reactants & Reagents & List-II: Reaction Name array l (a) Benzene diazonium chloride ( C ₆ H ₅ ~N ₂⁺ Cl ⁻) reacting with CuCl ₂ to form array & Sandmeyer reaction chlorobenzene array ll (b) Benzene diazonium chloride ( C ₆ H ₅ ~N ₂⁺ Cl ⁻ ) reacting with Cu , HCl to form array & Gattermann reaction chlorobenzene (c) 2 CH ₃ CH ₂ Cl +2 Na in ether to form butane ( C ₄ H ₁₀)

Options

  1. Aa → iii , b → iv , c → i , d → ii
  2. Ba → ii , b → i , c → iv , d → iii
  3. Ca → iii , b → i , c → iv , d → ii
  4. Da → ii , b → iv , c → i , d → iii

Correct answer

D. a → ii , b → iv , c → i , d → iii

Step-by-step solution

a → ii Sand Meyer reaction b → iv Gatterman reaction c → i Wurtz reaction d → iii Fittig reaction The Wurtz reaction is a very useful reaction in the fields of organic chemistry and organometallic chemistry for the formation of alkanes. In this reaction, two different alkyl halides are coupled to yield a longer alkane chain with the help of sodium and dry ether solution.

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