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NEET
Exam
NEET
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

NEET · Chemistry · Carboxylic Acid Derivatives

Match the following Column-1 Acid Column-2 pKa value A) CH _ 3 COOH...

Match the following
Column-1
Acid
Column-2
pKapKa value
A) CH3COOH{CH}_{3}COOH I) 0.230 . 23
B) F3CCOOH{F}_{3}CCOOH II) 3.413 . 41
C) Match the following Column-1 Acid Column-2 pKa value A) CH _ 3 COOH I) 0 . 23 B) F _ 3 CCOOH II) 3 . 41 C) III) 4 . 19 III) 4.194 . 19
D) Match the following Column-1 Acid Column-2 pKa value A) CH _ 3 COOH I) 0 . 23 B) F _ 3 CCOOH II) 3 . 41 C) III) 4 . 19 IV) 4.764 . 76
The correct match is

Options

  1. A
    A B C D
    IV. I III II
  2. B
    A B C D
    I IV. II III
  3. C
    A B C D
    IV I. II III
  4. D
    A B C D
    IV III II I

Correct answer

A.

A B C D
IV. I III II

Step-by-step solution

The acidity of carboxylic acid is directly proportional to the acid dissociation constant. But it is inversely proportional to the pKa{pK}_{a} value because the pKa{pK}_{a} is equal to the −logKa- {logK}_{a}. So, the order of acidity of given acids depends upon the −M,−I- M, - I effect. It is directly proportional to the −M,−I- M, - I effect.

The acetic acid is least acidic. So, it has the pKa{pK}_{a} value of 4.764 . 76. After that acidity of benzoic acid. So, it has the pKa{pK}_{a} value of 4.194 . 19. After that acidity of p−p -nitrobenzoic acid. So, it has the pKa{pK}_{a} value of 3.413 . 41. The compound F3CCOOH{F}_{3}CCOOH is most acidic. So, it has the pKa{pK}_{a} value of 0.230 . 23.

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