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BITSAT 2024
Exam
BITSAT
Year
2024
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

BITSAT 2024 · Chemistry · Chemical Bonding and Molecular Structure

The hybridisation scheme for the central atom includes a d -orbital...

The hybridisation scheme for the central atom includes a dd-orbital contribution inThe hybridisation scheme for the central atom includes a d -orbital contribution in

Options

  1. AI3−\mathrm{I}_3^{-}
  2. BPCl3\mathrm{PCl}_3
  3. CNO3−\mathrm{NO}_3^{-}
  4. DH2Se\mathrm{H}_2 \mathrm{Se}

Correct answer

A. I3−\mathrm{I}_3^{-}

Step-by-step solution

I3−\mathrm{I}_3^{-} is linear with central iodine atom undergoing sp3ds p^3 d-hybridisation and three lone pairs occupying equatorial position. Thus, this structure include dd-orbital contribution to the hybridisation scheme. The structure is, The hybridisation scheme for the central atom includes a d -orbital contribution in PCl3\mathrm{PCl}_3 structure is sp3s p^3-hybridised with one lone pair. NO3−\mathrm{NO}_3^{-} is sp2s p^2-hybridised and H2Se\mathrm{H}_2 \mathrm{Se} is sp3s p^3 - hybridised with two lone pairs of Se atom.
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