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BITSAT Chemical Bonding and Molecular Structure PYQs with Solutions

43 previous year questions from Chemical Bonding and Molecular Structure (BITSAT Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

43 questionsChemistry2009–2024Answers + solutions

About Chemical Bonding and Molecular Structure PYQs

Chemical Bonding and Molecular Structure has 43 previous year questions in the Quantrex Academy BITSAT Chemistry bank. The 43 questions in this list come from BITSAT (43), spanning 2009 to 2024. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2024: 7
  • 2023: 2
  • 2022: 3
  • 2021: 7
  • 2020: 1
  • 2018: 4
  • 2017: 2
  • 2016: 1
  • 2015: 3
  • 2014: 3
  • 2013: 1
  • 2012: 3

Chemical Bonding and Molecular Structure questions with solutions

1

Intramolecular hydrogen bonding is found in

BITSAT 2024 Solution
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2

The hybridisation scheme for the central atom includes a d -orbital contribution in

BITSAT 2024 Solution
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3

In the following species, how many species have same magnetic moment? (i) Cr^ 2+ (ii) Mn^ 3+ (iii) Ni^ 3+ (iv) Sc^ 2+ (v) Zn^ 2+ (vi) V^ 3+ (vii) Ti^ +

BITSAT 2024 Solution
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4

The spin only magnetic moment of Fe^ 3+ ion (in BM) is approximately.

BITSAT 2024 Solution
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5

Which one of the following compounds is having maximum 'lone pair-lone pair' electron repulsions?

BITSAT 2024 Solution
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6

Identify the species having one π -bond and maximum number of canonical forms from the following:

BITSAT 2024 Solution
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7

sp^3 ~d^2 hybridisation is not displayed by :

BITSAT 2024 Solution
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8

Energy required to completely separate one mole of a solid ionic compound into gaseous. constituent ions is called

BITSAT 2023 Solution
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9

Which of the following pairs will form the most stable ionic bond?

BITSAT 2023 Solution
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10

OF and F_2 can be compared in terms of

BITSAT 2022 Solution
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11

In which pair or pairs is the stronger bond found in the first species? I. O_2^ 2- , O_2 ; II. N_2, N_2^ + III. NO^ + , NO^ -

BITSAT 2022 Solution
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12

In the molecules CH_4, NF_3, NH_4^ + and H_2 O

BITSAT 2022 Solution
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13

Which one of the following ions has the maximum magnetic moment?

BITSAT 2021 Solution
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14

Which of the following represents the correct order of Cl- O bond lengths in ClO^ - , ClO_ 2 ^ - , ClO_ 3 ^ - , ClO_ 4 ^ - ?

BITSAT 2021 Solution
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15

Which of the following has the highest p π-p π bonding tendency?

BITSAT 2021 Solution
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16

Which of the following does not contain any coordinate bond?

BITSAT 2021 Solution
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17

Which of the following set contains species having same angle around the central atom?

BITSAT 2021 Solution
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18

In XeF_ 2 , XeF_ 4 , XeF_ 6 the number of lone pairs on Xe are respectively

BITSAT 2021 Solution
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19

Which one of the following molecules will form a linear polymeric structure due to hydrogen bonding?

BITSAT 2021 Solution
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20

In the reaction 2 PCl_ 5 leftharpoons PCl_ 4 ^ + +PCl_ 6 ^ - , the change in hybridisation is from

BITSAT 2020 Solution
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21

The incorrect statement about carbonate ( CO _ 3 ^ 2 - ) ion is,

BITSAT 2018 Solution
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22

Which substance has a dipole moment?

BITSAT 2018 Solution
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23

Which of the following diatomic molecules would be stabilised by the removal of an electron?

BITSAT 2018 Solution
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24

Valence electrons in the element A are 3 and that in element B are 6 . Most probable compound formed from A and B is

BITSAT 2018 Solution
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25

Which of the following are isoelectronic species? I. + C H _ 3 II. NH _ 2 ^ - III. NH _ 4 ^ + IV. NH _ 3

BITSAT 2017 Solution
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26

Which of the following show maximum bond-order?&

BITSAT 2017 Solution
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27

In PO_ 4 ^ 3- , the formal charge on each oxygen atom and the P-O bond order respectively are

BITSAT 2016 Solution
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28

The boiling point of alkyl halide are higher than those of corresponding alkanes because of

BITSAT 2015 Solution
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29

Which one of the following does not follow octate rule?

BITSAT 2015 Solution
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30

Which of the following molecule/ion has all the three types of bonds, electrovalent, covalent and co-ordinate:

BITSAT 2015 Solution
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31

Which one of the following pairs is isostructural (i.e., having the same shape and hybridization)?

BITSAT 2014 Solution
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32

N_ 2 and O_ 2 are converted into mono anions, N_ 2 ^ - and O_ 2 ^ - respectively. Which of the following statements is wrong ?

BITSAT 2014 Solution
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33

The correct order of increasing C-O bond length CO, CO_ 3 ^ 2- , CO_ 2 is:

BITSAT 2014 Solution
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34

Using MOT, which of the following pairs denote paramagnetic species?

BITSAT 2013 Solution
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35

The vapour pressure of is higher than due to

BITSAT 2012 Solution
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36

Bond enthalpies of H_ 2 , X_ 2 and HX are in the ratio 2: 1: 2. If enthalpy of formation of HX is -50 kJmol^ -1 , the bond enthalpy of X_ 2 is

BITSAT 2012 Solution
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37

The boiling point of water is exceptionally high because

BITSAT 2012 Solution
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38

A σ bonded molecule MX_ 3 is T-shaped. The number of non bonded pair of electrons is

BITSAT 2011 Solution
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39

The correct bond order in the following species is:

BITSAT 2011 Solution
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40

Which of the following statements is/are true? 1. PH_ 5 and BiCl_ 5 do not exist. 2. p π-d π bond is present in SO_ 2 3.I_ 3 ^ + has bent geometry. 4. SeF_ 4 and CH_ 4 , have same

BITSAT 2010 Solution
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41

Which of the following two are isostructural?

BITSAT 2009 Solution
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42

Which of the following has zero dipole moment?

BITSAT 2009 Solution
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43

Interparticle forces present in nylon 66 are

BITSAT 2009 Solution
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