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Chemical Bonding and Molecular Structure — BITSAT Chemistry PYQs

43 previous year questions from Chemical Bonding and Molecular Structure with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

43 questionsChemistrySolutions on every page
1

Intramolecular hydrogen bonding is found in

BITSAT 2024 Solution
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2

The hybridisation scheme for the central atom includes a d -orbital contribution in

BITSAT 2024 Solution
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3

In the following species, how many species have same magnetic moment? (i) Cr ²⁺ (ii) Mn ³⁺ (iii) Ni ³⁺ (iv) Sc ²⁺ (v) Zn ²⁺ (vi) V ³⁺ (vii) Ti ⁺

BITSAT 2024 Solution
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4

The spin only magnetic moment of Fe ³⁺ ion (in BM) is approximately.

BITSAT 2024 Solution
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5

Which one of the following compounds is having maximum 'lone pair-lone pair' electron repulsions?

BITSAT 2024 Solution
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6

Identify the species having one -bond and maximum number of canonical forms from the following:

BITSAT 2024 Solution
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7

sp ^3 ~d ^2 hybridisation is not displayed by :

BITSAT 2024 Solution
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8

Energy required to completely separate one mole of a solid ionic compound into gaseous. constituent ions is called

BITSAT 2023 Solution
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9

Which of the following pairs will form the most stable ionic bond?

BITSAT 2023 Solution
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10

OF and F ₂ can be compared in terms of

BITSAT 2022 Solution
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11

In which pair or pairs is the stronger bond found in the first species? I. O ₂²⁻, O ₂ ; II. N ₂, ~N ₂⁺ III. NO ⁺, NO ⁻

BITSAT 2022 Solution
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12

In the molecules CH ₄, NF ₃, NH ₄⁺ and H ₂ O

BITSAT 2022 Solution
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13

Which one of the following ions has the maximum magnetic moment?

BITSAT 2021 Solution
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14

Which of the following represents the correct order of Cl - O bond lengths in ClO ⁻, ClO ₂⁻, ClO ₃⁻, ClO ₄⁻ ?

BITSAT 2021 Solution
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15

Which of the following has the highest p -p bonding tendency?

BITSAT 2021 Solution
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16

Which of the following does not contain any coordinate bond?

BITSAT 2021 Solution
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17

Which of the following set contains species having same angle around the central atom?

BITSAT 2021 Solution
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18

In XeF ₂, XeF ₄, XeF ₆ the number of lone pairs on Xe are respectively

BITSAT 2021 Solution
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19

Which one of the following molecules will form a linear polymeric structure due to hydrogen bonding?

BITSAT 2021 Solution
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20

In the reaction 2 PCl ₅ PCl ₄⁺+ PCl ₆⁻ , the change in hybridisation is from

BITSAT 2020 Solution
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21

The incorrect statement about carbonate CO 3 2 - ion is,

BITSAT 2018 Solution
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22

Which substance has a dipole moment?

BITSAT 2018 Solution
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23

Which of the following diatomic molecules would be stabilised by the removal of an electron?

BITSAT 2018 Solution
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24

Valence electrons in the element A are 3 and that in element B are 6 . Most probable compound formed from A and B is

BITSAT 2018 Solution
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25

Which of the following are isoelectronic species? I. C + H 3 II. NH 2 - III. NH 4 + IV. NH 3

BITSAT 2017 Solution
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26

Which of the following show maximum bond-order?

BITSAT 2017 Solution
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27

In PO ₄³⁻, the formal charge on each oxygen atom and the P - O bond order respectively are

BITSAT 2016 Solution
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28

The boiling point of alkyl halide are higher than those of corresponding alkanes because of

BITSAT 2015 Solution
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29

Which one of the following does not follow octate rule?

BITSAT 2015 Solution
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30

Which of the following molecule/ion has all the three types of bonds, electrovalent, covalent and co-ordinate:

BITSAT 2015 Solution
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31

Which one of the following pairs is isostructural (i.e., having the same shape and hybridization)?

BITSAT 2014 Solution
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32

N ₂ and O ₂ are converted into mono anions, N ₂⁻ and O ₂⁻ respectively. Which of the following statements is wrong ?

BITSAT 2014 Solution
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33

The correct order of increasing C - O bond length CO , CO ₃²⁻, CO ₂ is:

BITSAT 2014 Solution
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34

Using MOT, which of the following pairs denote paramagnetic species?

BITSAT 2013 Solution
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35

The vapour pressure of is higher than due to

BITSAT 2012 Solution
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36

Bond enthalpies of H ₂, X ₂ and HX are in the ratio 2: 1: 2 . If enthalpy of formation of HX is -50 ~kJ mol ⁻¹, the bond enthalpy of X ₂ is

BITSAT 2012 Solution
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37

The boiling point of water is exceptionally high because

BITSAT 2012 Solution
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38

A bonded molecule MX ₃ is T-shaped. The number of non bonded pair of electrons is

BITSAT 2011 Solution
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39

The correct bond order in the following species is:

BITSAT 2011 Solution
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40

Which of the following statements is/are true? 1. PH ₅ and BiCl ₅ do not exist. 2. p -d bond is present in SO ₂ 3. I ₃⁺ has bent geometry. 4. SeF ₄ and CH ₄ , have same shape.

BITSAT 2010 Solution
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41

Which of the following two are isostructural?

BITSAT 2009 Solution
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42

Which of the following has zero dipole moment?

BITSAT 2009 Solution
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43

Interparticle forces present in nylon 66 are

BITSAT 2009 Solution
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