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BITSAT 2012
Exam
BITSAT
Year
2012
Subject
Chemistry
Chapter
Chemical Equilibrium

BITSAT 2012 · Chemistry · Chemical Equilibrium

The reaction, SO_ 2 +Cl_ 2 SO_ 2 Cl_ 2 is exothermic and...

The reaction, SO2+Cl2⟶SO2Cl2\mathrm{SO}_{2}+\mathrm{Cl}_{2} \longrightarrow \mathrm{SO}_{2} \mathrm{Cl}_{2} is exothermic and reversible. A mixture of SO2(g)\mathrm{SO}_{2}(\mathrm{ g}), Cl2(g)\mathrm{Cl}_{2}(\mathrm{ g}) and SO2Cl2(l)\mathrm{SO}_{2} \mathrm{Cl}_{2}(\mathrm{l}) is at equilibrium in a closed container. Now a certain quantity of extra SO2\mathrm{SO}_{2} is introduced into the container, the volume remaining the same. Which of the following is/are true?

Options

  1. AThe pressure inside the container will not change.
  2. BThe temperature will not change.
  3. CThe temperature will increase.
  4. DThe temperature will decrease.

Correct answer

C. The temperature will increase.

Step-by-step solution

Byaddition of SO2\mathrm{SO}_{2}, equilibrium will shift to RHS which is exothermic. Hence temp, will increase.
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