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BITSAT 2014
Exam
BITSAT
Year
2014
Subject
Chemistry
Chapter
Chemical Kinetics

BITSAT 2014 · Chemistry · Chemical Kinetics

A gaseous reaction X_ 2 ( g) Y+(1)/(2) Z(g) There is increase in...

A gaseous reaction X2(g)⟶Y+12Z(g)\mathrm{X}_{2}(\mathrm{ g}) \longrightarrow \mathrm{Y}+\frac{1}{2} \mathrm{Z}(\mathrm{g}) There is increase in pressure from 100mm100 \mathrm{ mm} to 120 mm\mathrm{mm} in 5 minutes. The rate of disappearance of X2\mathrm{X}_{2} is

Options

  1. A8mmmin−18 \mathrm{ mm} \mathrm{ min}^{-1}
  2. B2mmmin−12 \mathrm{ mm} \mathrm{ min}^{-1}
  3. C16mmmin−116 \mathrm{ mm} \mathrm{ min}^{-1}
  4. D4mmmin⁡−14 \mathrm{ mm} \min ^{-1}

Correct answer

A. 8mmmin−18 \mathrm{ mm} \mathrm{ min}^{-1}

Step-by-step solution

The increase in pressure shows the increase in conc. of ZZ. Rate of appearance of Z=120−1005=4mmmin−1Z=\frac{120-100}{5}=4 \mathrm{ mm} \mathrm{ min}^{-1} Rate of disappearance of X2=2×\mathrm{X}_{2}=2 \times rate of appearance of Z=2×4mmmin−1=8mmmin−1Z=2 \times 4 \mathrm{ mm} \mathrm{ min}^{-1}=8 \mathrm{ mm} \mathrm{ min}^{-1}
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