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BITSAT Chemical Kinetics PYQs with Solutions

33 previous year questions from Chemical Kinetics (BITSAT Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

33 questionsChemistry2009–2024Answers + solutions

About Chemical Kinetics PYQs

Chemical Kinetics has 33 previous year questions in the Quantrex Academy BITSAT Chemistry bank. The 33 questions in this list come from BITSAT (33), spanning 2009 to 2024. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2024: 6
  • 2023: 2
  • 2021: 2
  • 2020: 1
  • 2019: 3
  • 2018: 3
  • 2017: 2
  • 2016: 2
  • 2015: 2
  • 2014: 3
  • 2013: 2
  • 2012: 1

Chemical Kinetics questions with solutions

1

For the reaction 2 SO_2+O_2 leftharpoons 2 SO_3 , the rate of disappearance of O_2 is 2 × 10^ -4 mol L^ -1 ^ -1 . The rate appearance of SO_3 is

BITSAT 2024 Solution
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2

If for a first order reaction, the value of A and E_a are 4 × 10^ 13 s^ -1 and 98.6 kJ mol^ -1 respectively, then at what temperature will its half life period be 10 minutes?

BITSAT 2024 Solution
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3

In the chemical reaction A arrow B , what is the order of the reaction? Given that, the rate of reaction doubles if the concentration of A is increased four times.

BITSAT 2024 Solution
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4

Calculate the activation energy of a reaction, whose rate constant doubles on raising the temperature from 300 K to 600 K.

BITSAT 2024 Solution
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5

In the reaction, A arrow products, If the concentration of the reactant is doubled rate of the reaction remains unchanged. The order of the reaction with respect to A is

BITSAT 2024 Solution
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6

In a first order reaction, the concentration of the reactant, decreases from 0.8 M to 0.4 M in 15 minutes. The time taken for the concentration to change from 0.1 M to 0.025 M is

BITSAT 2024 Solution
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7

For the decomposition of azomethane, CH_3 N_2 CH_3( g) arrow CH_3 CH_3( g)+N_2( g) a first order reaction, the variation in partial pressure with time at 600 K is given as The

BITSAT 2023 Solution
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8

Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that follows Arrhenius equation is

BITSAT 2023 Solution
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9

In a 1 st order reaction, reactant concentration C varies with time t as :

BITSAT 2021 Solution
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10

XmL of H_ 2 gas effuses through a hole in a container in 5 seconds. The time taken for the effusion of the same volume of the gas specified below under identical conditions is :

BITSAT 2021 Solution
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11

A radioactive isotope having a half - life period of 3 days was received after 12 days. If 3 g of the isotope is left in the container, what would be the initial mass of the

BITSAT 2020 Solution
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12

Given the hypothetical reaction mechanism A I ⟶ B II ⟶ C III ⟶ D IV → E and the rate as Species formed Rate of its information B 0. 002mol / h per mole

BITSAT 2019 Solution
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13

For the chemical reaction 2 O _ 3 ⟶ 3 O _ 2 , the reaction proceeds as follows O _ 3 ⇌ O _ 2 + O (Fast) O + O _ 3 ⟶ 2 O _ 2 ,& (Slow) the rate law expression should be given as

BITSAT 2019 Solution
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14

For a reversible& reaction, A ⇌ B ,& which one of the following statement is wrong from the given energy& profile diagram?

BITSAT 2019 Solution
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15

Under the same reaction conditions, initial concentration of 1 . 386mol dm ^ - 3 of a substance becomes half in 40s and 20s through first order and zero order kinetics

BITSAT 2018 Solution
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16

The rate of a reaction triples when temperature changes from 20 ^ 0 C to 50 ^ 0 C . The energy of activation for the reaction is (R = 8 . 314 JK ^ - 1 mol ^ - 1 )

BITSAT 2018 Solution
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17

Which of the following expression is correct for the rate of reaction given below ? 5 Br ^ - (aq) + BrO _ 3 ^ - (aq) + 6H^ + (aq) ⟶ 3 Br _ 2 (aq) + 3 H _ 2 O (l)

BITSAT 2018 Solution
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18

For an endothermic reaction, where Δ H represent the enthalpy of reaction in kJ mol ^ - 1 , the minimum value for energy of activation (for forward reaction) will be

BITSAT 2017 Solution
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19

A graph is plotted between log K versus (1)/(T) for calculation of activation energy ( E _ a ) . The correct plot is

BITSAT 2017 Solution
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20

Consider the reaction : Cl_ 2 (a q)+H_ 2 ~S(a q) arrow S(s)+2 H^ + (a q)+2 Cl^ - (a q) The rate equation for this reaction is rate =k[Cl_ 2 ][H_ 2 ~S] Which of these mechanisms

BITSAT 2016 Solution
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21

In the reaction, P+Q ? R+S The time taken for 75 \% reaction of P is twice the time taken for 50 \% reaction of P . The concentration of Q varies with reaction time as shown in

BITSAT 2016 Solution
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22

The unit of rate constant for reactions of second order is

BITSAT 2015 Solution
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23

In a first order reaction with time the concentration of the reactant decreases

BITSAT 2015 Solution
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24

The reduction of peroxydisulphate ion by I ion is expressed by S_ 2 O_ 8 ^ 2- +3 I^ - arrow 2 SO_ 4 ^ 2- +I_ 3 ^ - . If rate of disappearance of I^ - is 9 / 2 × 10^ -3 mol lit ^

BITSAT 2014 Solution
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25

A gaseous reaction X_ 2 ( g) Y+(1)/(2) Z(g) There is increase in pressure from 100 mm to 120 mm in 5 minutes. The rate of disappearance of X_ 2 is

BITSAT 2014 Solution
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26

Two substances R and S decompose in solution independently, both following first order kinetics. The rate constant of R is twice that of S . In an experiment, the solution

BITSAT 2014 Solution
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27

Velocity constant of a reaction at 290 K was found to be 3.2 × 10^ -3 . At 300 K it will be

BITSAT 2013 Solution
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28

At high pressure, the entire surface gets covered by a monomolecular layer of the gas follows

BITSAT 2013 Solution
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29

2 N_ 2 O_ 5 leftharpoons 4 NO_ 2 +O_ 2 If rate and rate constant for above reaction are 2.40 × 10^ -5 mol L^ -1 s^ -1 and 3 × 10^ -5 s^ -1 respectively, then calculate the

BITSAT 2012 Solution
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30

During the kinetic study of the reaction, 2 A+B arrow C+D , following results were obtained: Run [A]/ mol L^ -1 [ B]/ mol L^ -1 Initial rate of formation of D/ mol L^ -1 min^ -1 I

BITSAT 2011 Solution
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31

The activation energy for a simple chemical reaction A arrow B is E_ a in forward direction. The activation energy for reverse reaction

BITSAT 2010 Solution
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32

The following data are for the decomposition of ammonium nitrite in aqueous solution : The order of reaction is:

BITSAT 2010 Solution
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33

The chemical reaction 2 O_ 3 3 O_ 2 proceeds as follows: rate law expression should be:

BITSAT 2009 Solution
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