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BITSAT 2020
Exam
BITSAT
Year
2020
Subject
Chemistry
Chapter
Coordination Compounds

BITSAT 2020 · Chemistry · Coordination Compounds

The d -electron configurations of Cr^ 2+ , Mn^ 2+ , Fe^ 2+ and Co^...

The dd -electron configurations of Cr2+,Mn2+,Fe2+\mathrm{Cr}^{2+}, \mathrm{Mn}^{2+}, \mathrm{Fe}^{2+} and Co2+\mathrm{Co}^{2+} are d4,d5,d6d^{4}, d^{5}, d^{6} and d7d^{7} respectively. Which one of the following will exhibit the lowest paramagnetic behaviour? (Atomic no. Cr=24,Mn=25,Fe=26,Co=27)\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27)The d -electron configurations of Cr^ 2+ , Mn^ 2+ , Fe^ 2+ and Co^ 2+ are d^ 4 , d^ 5 , d^ 6 and d^ 7 respectively.

Options

  1. A\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}
  2. B\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}
  3. C\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}
  4. D\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}

Correct answer

A. \left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}

Step-by-step solution

The d -electron configurations of Cr^ 2+ , Mn^ 2+ , Fe^ 2+ and Co^ 2+ are d^ 4 , d^ 5 , d^ 6 and d^ 7 respectively.
∴\therefore Since Co2+\mathrm{Co}^{2+} has lowest no. of unpaired electrons hence lowest paramagnetic behaviour is shown by \left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}
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