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BITSAT 2013
Exam
BITSAT
Year
2013
Subject
Chemistry
Chapter
Coordination Compounds

BITSAT 2013 · Chemistry · Coordination Compounds

The pair in which both species have same magnetic moment (spin...

The pair in which both species have same magnetic moment (spin onlyvalue) is:The pair in which both species have same magnetic moment (spin onlyvalue) is:

Options

  1. A\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+},[CoCI4]2−\left[\mathrm{CoCI}_{4}\right]^{2-}
  2. B[Cr(H2O6)2+,[Fe(H2O)6]3+\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}_{6}\right)^{2+},\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+}\right.
  3. C\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right)^{2+},[Cr(H2O)6]2+\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}
  4. D[CoCl4)2−,\left[\mathrm{CoCl}_{4}\right)^{2-},\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}

Correct answer

B. [Cr(H2O6)2+,[Fe(H2O)6]3+\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}_{6}\right)^{2+},\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+}\right.

Step-by-step solution

[Cr(H2O)6]2+Cr\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+} \mathrm{Cr} is in Cr2+\mathrm{Cr}^{2+} form The pair in which both species have same magnetic moment (spin onlyvalue) is:
In [Fe(H2O)]2+Fe2+\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{2+} \mathrm{Fe}^{2+} form. Both will have 4 unpaired electrons.
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