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BITSAT 2019
Exam
BITSAT
Year
2019
Subject
Chemistry
Chapter
Structure of Atom

BITSAT 2019 · Chemistry · Structure of Atom

If the photon of wavelength 150 pm strikes an atom and one of its...

If the photon of wavelength 150150 pm strikes an atom and one of its inner bound electron is ejected out with a velocity of 1.5×107m/s1. 5 \times {10}^{7}m / s,& what is the energy with which it is bound to the nucleus?

Options

  1. A1.2×102eV1. 2 \times {10}^{2}eV
  2. B2.15×103eV2. 15 \times {10}^{3}eV
  3. C7.6×103eV7. 6 \times {10}^{3}eV
  4. D8.12×103eV8. 12 \times {10}^{3}eV

Correct answer

C. 7.6×103eV7. 6 \times {10}^{3}eV

Step-by-step solution

Total energy (E)\left(E\right) of any photon is given by the relation : E=hcλE = \dfrac{hc}{λ}

Where, h=h = Planck's constant =6.6×10−34Js= 6 . 6 \times {10}^{- 34}Js

c=c = Velocity of light =3×108m/s= 3 \times {10}^{8}m / s

λ=\lambda = wavelength =1.5×10−10m,= 1 . 5 \times {10}^{- 10}m, i.e, \left(150pm\right)</p><p>Thus,</p><p>Thus,E = \dfrac{hc}{λ} = \dfrac{6 . 6 \times {10}^{- 34} \times 3 \times {10}^{8}}{1 . 5 \times {10}^{- 10}}; E = 1 . 32 \times {10}^{- 15}Jand,energyofejectedelectron(E′)and, energy of ejected electron \left(E^{'}\right)

E′=12mv2E^{'} = \dfrac{1}{2}{mv}^{2},

where,

m=m = mass of electron =9.1×10−31kg= 9 . 1 \times {10}^{- 31}kg

v=v = velocity of electron

=1.5×107m/s= 1 . 5 \times {10}^{7}m / s

E′=12mv2=12×9.1×10−31×(1.5×107)2E^{'} = \dfrac{1}{2}{mv}^{2} = \dfrac{1}{2} \times 9 . 1 \times {10}^{- 31} \times \left(1 . 5 \times {10}^{7}\right)2

E′=1.024×10−16E^{'} = 1 . 024 \times {10}^{- 16}

Thus, total energy of photon = Binding energy of electron

\left(B\right)+energyofejectedelectron(E′)+ energy of ejected electron \left(E^{'}\right)

Thus, 1 . 32 \times {10}^{- 15} = \left(B\right) + \left( E\right)</p><p></p><p>∴ \left(B\right) = \left( E\right) - \left(E^{'}\right) = \left[1 . 32 \times {10}^{- 15}\right] - \left[1 . 024 \times {10}^{- 16}\right]

=1.2176×10−15J= 1 . 2176 \times {10}^{- 15}J

=1.2176×10−151.6×10−19= \dfrac{1 . 2176 \times {10}^{- 15}}{1 . 6 \times {10}^{- 19}} eV = 7 . 6 \times {10}^{3}eV</p></blockquote></p></blockquote>

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