Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Advanced 2020Paper 1
Exam
JEE Advanced
Year
2020
Paper
Paper 1
Subject
Chemistry
Chapter
Chemical Equilibrium

JEE Advanced 2020 · Paper 1 · Chemistry · Chemical Equilibrium

Consider the reaction A ⇌ B at 1000K . At time t ^ ' , the...

Consider the reaction A⇌BA ⇌ B at 1000K1000K. At time t′{t}^{'}, the temperature of the system was increased to 2000K2000K and the system was allowed to reach equilibrium. Throughout this experiment the partial pressure of AA was maintained at 11 bar. Given below is the plot of the partial pressure of BB with time. What is the ratio of the standard Gibbs energy of the reaction at 1000K1000K to that at 2000K2000K?

 Consider the reaction A ⇌ B at 1000K . At time t ^ ' , the temperature of the system was increased to 2000K and the

Correct answer

0.25

Step-by-step solution

Use ΔG°=−RTlnKP\Delta G ° = - RTlnKP at equilibrium

ΔG1∘=−RT1lnKP1{\Delta G}_{1}^{∘} = - {RT}_{1}ln{\text{K}}_{{\text{P}}_{1}} ...... (1)( 1 )

ΔG2∘=−RT2lnKP2{\Delta G}_{2}^{∘} = - {RT}_{2}ln{\text{K}}_{\text{P}2} ..... (2)( 2 )

ΔG1∘ΔG2∘=T1T2×lnKP1lnKP2{\Delta G}_{1}^{∘}{\Delta G}_{2}^{∘} = \dfrac{{\text{T}}_{1}}{{\text{T}}_{2}} \times \dfrac{{lnK}_{{\text{P}}_{1}}}{{lnK}_{{\text{P}}_{2}}}

==10002000\begin{array}{ll}1000 \\ 2000\end{array}×\timesln⁡(10)ln⁡(100)\begin{array}{ll}\ln ( 10 ) \\ \ln ( 100 )\end{array}$</p><p></p><p>= \dfrac{1}{2} \times \dfrac{1}{2} = \dfrac{1}{4} = 0 . 25$

Practice Chemical Equilibrium on Quantrex Academy →

More from Chemical Equilibrium

Consider the following reactions in which all the reactants and products are present in… JEE Main 2026Solid carbon, CaO and CaCO _3 are mixed and allowed to attain equilibrium at T K.… JEE Main 2026In a closed flask at 600 K, one mole of X _2 Y _4 (g) attains equilibrium as given below… JEE Main 2026One mole each of He and A(g) are taken in a 10 L closed flask and heated to 400 K to… JEE Main 2026The reaction A(g) leftharpoons B(g) + C(g) was initiated with the amount ' a ' of A(g) .… JEE Main 2026The values of pressure equilibrium constant recorded at different temperatures for the… JEE Main 2026For the following reaction at 50° C and at 2 atm pressure, 2N_2O_5(g) leftharpoons… JEE Main 2026At T(K) , the equilibrium constant of A_2(g) + B_2(g) leftharpoons C(g) is 2.7 × 10^ -5 .… JEE Main 2026 Full Chemical Equilibrium list All JEE Advanced PYQs