JEE Advanced2023ChemistryElectrochemistryActual
Plotting 1 / Λ m against cΛ m for aqueous solutions of a monobasic weak acid ( HX ) resulted in a straight line with y - axis intercept of P and slope of S . The ratio P / S is Λ m = molar conductivity Λ m o = limiting molar conductivity c = molar concentration K a = dissociation constant of HX
Options
- AK a Λ m o
- BK a Λ m o / 2
- C2   K a Λ m o
- D1 / K a Λ m o
Correct answer
A. K a Λ m o
Step-by-step solution
The degree of dissociation is the ratio of molar conductivity to the limiting molar conductivity. α = Λ m Λ m o The equilibrium reaction is given below,                                                   HX ⇌ H + + X - initial                                     c