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Electrochemistry — JEE Main & Advanced Chemistry PYQs

526 previous year questions from Electrochemistry with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

526 questionsChemistrySolutions on every page
1

At 300 K, the molar conductivities of the aqueous solutions of three salts at two different concentrations are given below: Salt Concentration (M) Molar conductivity (S cm ^2 mol ⁻

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2

Given at 298 K: E^ _ Fe²⁺/Fe = X Volt; E^ _ Fe³⁺/Fe = Y Volt. The E^ _ Fe³⁺/Fe²⁺ in Volt at 298 K is given by:

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3

For a general redox reaction Anode : Red ₁ Ox ₁^ n₁^+ + n₁ e^- Cathode : Ox ₂ + n₂ e^- Red ₂^ n₂^- Which of the following statements is incorrect?

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4

Consider the following data. Electrolyte ^ _m (S cm ^2 mol ⁻¹ ) BaCl ₂ x₁ H ₂ SO ₄ x₂ HCl x₃ BaSO ₄ is sparingly soluble in water. If the conductivity of the saturated BaSO ₄ solut

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5

One half cell in a voltaic cell is constructed by dipping silver rod in AgNO₃ solution of unknown concentration, other half cell is Zn rod dipped in 1 molar solution of ZnSO₄ . A v

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6

At 298 K , the molar conductivity of x % (w/w) MX solution (aqueous) is 123.5 S cm ^2 mol ⁻¹ . The conductance of same solution is 1.9 10⁻³ S . The value of x is _______ 10⁻² . (Gi

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7

An electrochemical cell, consist of the following two redox couples, M^ x+ (aq)/M(s)[E_ red ^ =+0.15 V ] and Fe³⁺(aq)/Fe(s)[E_ red ^ =-0.036 V ] . The cell EMF (E_ cell ) is record

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8

Consider the following two half-cell reactions along with the standard reduction potential given: CO₂ + 6H^+ + 6e^- CH₃ OH + H₂ O E°_ red = 0.02 V 1 2 O₂ + 2H^+ + 2e^- H₂ O E°_ red

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9

An electrochemical cell is constructed using half cells in the direction of spontaneous change Fe(OH)₂(s) + 2e^- Fe(s) + 2OH^-(aq) E^ = -0.88 V and AgBr(s) + e^- Ag(s) + Br^-(aq) E

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10

For strong electrolyte _ m increases slowly with dilution and can be represented by the equation _ m = _ m ^ - Ac ^ 1 / 2 Molar conductivity values of the solutions of strong elect

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11

A volume of x , mL of 5 , M , NaHCO₃ solution was mixed with 10 , mL of 2 , M , H₂CO₃ solution to make an electrolytic buffer. If the same buffer was used in the following electroc

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12

Consider the following redox reaction taking place in acidic medium BH ₄⁻(a q)+ ClO ₃⁻(a q) H ₂ BO ₃⁻(a q)+ Cl ⁻(a q) If the Nernst equation for the above balanced reaction is E _

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13

Molar conductivity of a weak acid HQ of concentration 0.18 M was found to be 1 / 30 of the molar conductivity of another weak acid HZ with concentration of 0.02 M. If ^ Q ⁻ happene

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14

Electricity is passed through an acidic solution of Cu ²⁺ till all the Cu ²⁺ was exhausted, leading to the deposition of 300 mg of Cu metal. However, a current of 600 mA was contin

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15

Consider the above electrochemical cell where a metal electrode (M) is undergoing redox reaction by forming M ⁺ ( M M ⁺+ e ⁻ ) . The cation M ⁺ is present in two different concentr

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16

In the given electrochemical cell, Ag ( s )| AgCl ( s )| FeCl ₂( aq ), FeCl ₃( aq ) Pt ( s ) at 298 K, the cell potential ( E _ cell ) will increase when : A. Concentration of Fe ²

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17

Consider the following reduction processes : Al ³⁺+3 e ⁻ Al ( s ), E ⁰=-1.66 ~V Fe ³⁺+ e ⁻ Fe ²⁺, E ⁰=+0.77 ~V Co ³⁺+ e ⁻ Co ²⁺, E ⁰=+1.81 ~V Cr ³⁺+3 e ⁻ Cr ( s ), E ^ =-0.74 ~V Th

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18

Consider the following electrochemical cell : Pt | O ₂( ~g )(1 bar ) | HCl ( aq ) | M ²⁺( aq , 1.0 M ) M ( ~s ) The pH above which, oxygen gas would start to evolve at anode is _ _

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19

Consider the following electrochemical cell at 298 K Pt | HSnO ₂ ⁻( aq ) | Sn ( OH )₆ ²⁻( aq ) | OH ⁻( aq ) | Bi ₂ O ₃( ~s ) Bi ( s ) . If the reaction quotient at a given time is

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20

For a closed circuit Daniell cell, which of the following plots is the accurate one at a given temperature?

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21

MX is a sparingly soluble salt that follows the given solubility equilibrium at 298 K. MX ( s ) M ⁺( aq )+ X ⁻( aq ) ; K _ sp =10⁻¹⁰ If the standard reduction potential for M ⁺( aq

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22

The pH and conductance of a weak acid (HX) was found to be 5 and 4 10⁻⁵ ~S , respectively. The conductance was measured under standard condition using a cell where the electrode pl

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23

In an electrochemicalcell, dichromate ions in aqueous acidic medium are reduced to Cr ³⁺ . The current (in amperes) that flows through the cell for 48.25 minutes to produce 1 mole

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24

An electrochemical cell is fueled by the combustion of butane at 1 bar and 298 K . Its cell potential is X F 10^3 volts, where F is the Faraday constant. The value of X is . Use :

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25

Consider the following half cell reaction Cr ₂ O ₇²⁻( aq )+6 e ⁻+14 H ⁺( aq ) 2 Cr ³⁺( aq )+7 H ₂ O ( l ) The reaction was conducted with the ratio of [ Cr ³⁺ ]^2 [ Cr ₂ O ₇²⁻ ] =1

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26

Given below are two statements : 1 M aqueous solution of each of Cu ( NO ₃ )₂, AgNO ₃ , Hg ₂ ( NO ₃ )₂ ; Mg ( NO ₃ )₂ are electrolysed using inert electrodes, aligned & Given : E _

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27

1 Faraday electricity was passed through Cu ²⁺(1.5 M , 1 ~L ) / Cu and 0.1 Faraday was passed through Ag ⁺(0.2 M , 1 ~L ) / Ag electrolytic cells. After this the two cells were con

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28

Given below are two statements : Statement I : Mohr's salt is composed of only three types of ions-ferrous, ammonium and sulphate. Statement II : If the molar conductance at infini

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29

The molar conductance of an infinitely dilute solution of ammonium chloride was found to be 185 ~S ~cm ^2 ~mol ⁻¹ and the ionic conductance of hydroxyl and chloride ions are 170 an

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30

On charging the lead storage battery, the oxidation state of lead changes from x₁ to y₁ at the anode and from x₂ to y₂ at the cathode. The values of x₁, y₁, x₂, y₂ are respectively

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31

The standard cell potential ( E _ cell ^ ) of a fuel cell based on the oxidation of methanol in air that has been used to power television relay station is measured as 1.21 V. The

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32

40 mL of a mixture of CH ₃ COOH and HCl (aqueous solution) is titrated against 0.1 M NaOH solution conductometrically. Which of the following statement is correct?

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33

Correct order of limiting molar conductivity for cations in water at 298 K is :

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34

0.2 %( w / v ) solution of NaOH is measured to have resistivity 870.0 ~m ~m . The molar conductivity of the solution will be ______ 10^2 mS dm ^2 ~mol ⁻¹ . (Nearest integer)

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35

Consider the following electrochemical cell at standard condition. ( aligned & Au ( s ) | QH ₂, Q | NH ₄ X (0.01 M )| | Ag ⁺(1 M ) Ag ( s ) & E _ cell =+0.4 ~V aligned ) The couple

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36

O ₂ gas will be evolved as a product of electrolysis of : (A) an aqueous solution of AgNO ₃ using silver electrodes. (B) an aqueous solution of AgNO ₃ using platinum electrodes. (C

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37

Match List - I with List - II : ( array llll & List - I & List - II & Applications & Batteries / Cell (A) & Transistors & (I) Anode - Zn / Hg ; Cathode - HgO + C (B) & Hearing aids

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38

The molar conductivity of a weak electrolyte when plotted against the square root of its concentration, which of the following is expected to be observed ?

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39

The standard reduction potential values of some of the p-block ions are given below. Predict the one with the strongest oxidising capacity.

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40

For a ( Mg | Mg ²⁺( aq ) | | Ag ⁺( aq ) | Ag ) the correct Nernst Equation is :

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41

Electrolysis of 600 mL aqueous solution of NaCl for 5 min changes the pH of the solution to 12 . The current in Amperes used for the given electrolysis is ____. (Nearest integer).

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42

Given below is the plot of the molar conductivity vs concentration for KCl in aqueous solution. If, for the higher concentration of KCl solution, the resistance of the conductivity

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43

Based on the data given below : array ll E _ Cr ₂ O ₇²⁻ / Cr ³⁺ ^ =1.33 ~V & E _ Cl ₂ / Cl ^ (-) ^ =1.36 ~V E _ MnO ₄⁻ / Mn ²⁺ ^ =1.51 ~V & E _ Cr ³⁺ / Cr ^ =-0.74 ~V array the str

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44

For the given cell Fe ²⁺ _ ( aq ) + Ag ⁺ _ ( aq ) Fe _ ( aq ) ³⁺+ Ag _ ( s ) The standard cell potential of the above reaction is Given: array lr Ag ⁺+ e ⁻ Ag & E ^ = xV Fe ²⁺+2 e

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45

Standard electrode potentials for a few half cells are mentioned below : aligned & E _ Cu ²⁺ / Cu ^ =0.34 ~V , E _ Zn ²⁺ / Zn ^ =-0.76 ~V & E _ Ag ⁺ / Ag ^ =0.80 ~V , E _ Mg ²⁺ / M

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46

FeO ₄²⁻ +2.0 v Fe ³⁺ 0.8 v Fe ²⁺ -0.5 v Fe ^0 In the above diagram, the standard electrode potentials are given in volts (over the arrow). The value of E _ FeO ₄²⁻ / Fe ²⁺ ^ O is

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47

Given below are two statements : Statement (I) : Corrosion is an electrochemical phenomenon in which pure metal acts as an anode and impure metal as a cathode. Statement (II) : The

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48

A solution of aluminium chloride is electrolysed for 30 minutes using a current of 2 A . The amount of the aluminium deposited at the cathode is [Given : molar mass of aluminium an

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49

An aqueous solution of hydrazine ( N ₂ H ₄ ) is electrochemically oxidized by O ₂ , thereby releasing chemical energy in the form of electrical energy. One of the products generate

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50

In a conductometric titration, small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration, and the conductance is m

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51

Which out of the following is a correct equation to show change in molar conductivity with respect to concentration for a weak electrolyte, if the symbols carry their usual meaning

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52

Match List I with List II ( array |l|l|l|l| & List - I (Cell) & & List - II (Use/Property/Reaction) A. & Leclanche cell & I. & array l Converts energy of combustion into electrical

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53

The molar conductivity for electrolytes (A ) and (B ) are plotted against (C^ 1 / 2 ) as shown below. Electrolytes (A ) and (B ) respectively are :

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54

The standard reduction potentials at (298 ~K ) for the following half cells are given below : ( array ll Cr ₂ O ₇²⁻+14 H ⁺+6 e ⁻ 2 Cr ³⁺+7 H ₂ O , E ^ =1.33 ~V Fe ³⁺( aq )+3 e ⁻ Fe

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55

The emf of cell Tl ( | (0.001 M ) Tl ⁺ | | (0.01 M ) Cu ²⁺ | Cu ) is (0.83 ~V ) at (298 ~K ). It could be increased by :

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56

The reaction; ( 1 2 H _ 2( ~g ) + AgCl _ ( s ) H _ ( aq ) ⁺+ Cl _ ( aq ) ⁻+ Ag _ ( s ) ) occurs in which of the following galvanic cell :

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57

How can an electrochemical cell be converted into an electrolytic cell?

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58

A conductivity cell with two electrodes (dark side) are half filled with infinitely dilute aqueous solution of a weak electrolyte. If volume is doubled by adding more water at cons

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59

The quantity of silver deposited when one coulomb charge is passed through ( AgNO ₃ ) solution :

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60

For the electro chemical cell ( gathered If E _ ( M ²⁺ / M ) ^0=0.46 ~V and E _ ( x / X ²⁻ ) ^0=0.34 ~V . gathered ) Which of the following is correct?

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61

The reaction at cathode in the cells commonly used in clocks involves.

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62

Molar ionic conductivities of divalent cation and anion are (57 ~S ~cm ^2 ~mol ⁻¹ ) and (73 ~S ~cm ^2 ~mol ⁻¹ ) respectively. The molar conductivity of solution of an electrolyte w

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63

For a strong electrolyte, a plot of molar conductivity against (concentration) ( ^ 1 / 2 ) is a straight line, with a negative slope, the correct unit for the slope is

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64

Fuel cell, using hydrogen and oxygen as fuels, A. has been used in spaceship B. has as efficiency of (40 % ) to produce electricity C. uses aluminum as catalysts D. is eco-friendry

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65

What pressure (bar) of ( H ₂ ) would be required to make emf of hydrogen electrode zero in pure water at (25^ C ) ?

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66

One of the commonly used electrode is calomel electrode. Under which of the following categories, calomel electrode comes?

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67

The amount of electricity in Coulomb required for the oxidation of 1 mol of H 2 O to O 2 is ______ × 10 5 C .

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68

Consider the following redox reaction: MnO 4 - + H + + H 2 C 2 O 4 ⇌ Mn 2 + + H 2 O + CO 2 The standard reduction potentials are given as below E red ° E 0 MnO 4 - / Mn 2 + = + 1 .

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69

The potential for the given half cell at 298 K is - ............ × 10 - 2 V . 2 H ( aq ) + + 2 e - → H 2 ( g ) H + = 1 M , P H 2 = 2 atm (Given 2 . 303 RT / F = 0 . 06 V , log 2 =

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70

The values of conductivity of some materials at 298 .15 K in Sm − 1 are 2 .1 × 10 3 , 1 .0 × 10 − 16 , 1 .2 × 10 , 3 .91 , 1 .5 × 10 − 2 , 1 × 10 − 7 , 1 .0 × 10 3 . The number of

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71

The metals that are employed in the battery industries are A. Fe, B. Mn, C. Ni, D. Cr, E. Cd Choose the correct answer from the options given below:

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72

Identify the factor from the following that does not affect electrolytic conductance of a solution.

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73

One Faraday of electricity liberates x × 10 – 1 gram atom of copper from copper sulphate, x is______.

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74

Reduction potential of ions are given below: ClO 4 - IO 4 - BrO 4 - E ° = 1 . 19 V ; E ° = 1 . 65 V ; E ° = 1 . 74 V The correct order of their oxidising power is:

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75

A constant current was passed through a solution of AuCl 4 - ion between gold electrodes. After a period of 10 . 0 minutes, the increase in mass of cathode was 1 . 314 g . The tota

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76

The mass of zinc produced by the electrolysis of zinc sulphate solution with a steady current of 0 . 015 A for 15 minutes is _ _ _ _ × 10 - 4 g . (Atomic mass of zinc = 65 . 4 amu

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77

Which of the following statements is not correct about rusting of iron?

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78

The hydrogen electrode is dipped in a solution of pH = 3 at 25 ° C . The potential of the electrode will be - ______ × 10 - 2 V . 2 . 303 RT F = 0 . 059 V Round off the answer to t

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79

The mass of silver (Molar mass of Ag : 108 gmol - 1 ) displaced by a quantity of electricity which displaces 5600 mL of O 2 at S.T.P. will be _____ g.

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80

Plotting 1 / Λ m against cΛ m for aqueous solutions of a monobasic weak acid ( HX ) resulted in a straight line with y - axis intercept of P and slope of S . The ratio P

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81

The number of correct statements from the following is ___________ (A) Conductivity always decreases with decrease in concentration for both strong and weak electrolytes. (B) The n

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82

At 298 K , the standard reduction potential for Cu 2 + / Cu electrode is 0 . 34 V . Given : K sp Cu ( OH ) 2 = 1 × 10 - 20 Take 2 . 303 RT F = 0 . 059 V The reduction potentia

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83

A metal surface of 100 cm 2 area has to be coated with nickel layer of thickness 0 . 001 mm . A current of 2 A was passed through a solution of Ni NO 3 2 for ‘ x ’ seco

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84

For lead storage battery pick the correct statements A. During charging of battery, PbSO 4 on anode is converted into PbO 2 B. During charging of battery, PbSO 4 on cathode is conv

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85

The number of correct statements from the following is........... A. E cell is an intensive parameter B. A negative E o means that the redox couple is a stronger reducing agent tha

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86

In an electrochemical reaction of lead, at standard temperature, if E Pb 2 + / Pb o = m Volt and E Pb 4 + / Pb o = n Volt , then the value of E ° Pb 2 + / Pb 4 + is given by m

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87

The specific conductance of 0 . 0025 M acetic acid is 5 × 10 - 5 S cm - 1 at a certain temperature. The dissociation constant of acetic acid is ___________ × 10 - 7 .(Nea

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88

The reaction occurs in which of the given galvanic cell? 1 2 H 2 ( g ) + AgCl ( s ) ⇌ H + ( aq ) + Cl - ( aq ) + Ag ( s )

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89

The product, which is not obtained during the electrolysis of brine solution is

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90

The standard reduction potentials at 295 K for the following half cells are given below: NO 3 - + 4 H + + 3 e - → NO g + 2 H 2 O E o = 0 . 97 V V 2 + aq + 2 e - → V s E

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91

The standard electrode potential of M + / M in aqueous solution does not depend on

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92

1 × 10 - 5   M   AgNO 3 is added to 1   L of saturated solution of AgBr . The conductivity of this solution at 298   K is _ _ _ _ _ _ _ × 10 - 8 &#160

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93

At what pH , given half cell MnO 4 - ( 0 . 1 M ) ∣ Mn 2 + ( 0 . 001 M ) will have electrode potential of 1 . 282 V ? (Nearest Integer) Given E MnO 4 - / Mn 2 + o = 1 . 54 V ,

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94

The resistivity of a 0 . 8 M solution of an electrolyte is 5 × 10 - 3 Ωcm . Its molar conductivity is 10 4 Ω - 1 cm 2 mol - 1 . (Nearest integer)

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95

Which one of the following statements is correct for electrolysis of brine solution?

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96

The logarithm of equilibrium constant for the reaction Pd 2 + + 4 Cl - ⇌ PdCl 4 2 - is (Nearest integer) Given: 2 . 303 RT F = 0 . 06 V Pd ( aq ) 2 + + 2 e - ⇌ Pd ( s )

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97

The electrode potential of the following half cell at 298 K X X 2 + 0 . 001 M ‖ Y 2 + 0 . 01 M Y is _____ × 10 - 2 V (Nearest integer) Given : E X 2 + ∣ X 0 = - 2

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98

Consider the cell Pt s H 2 g , 1 atm H + aq , 1 M | Fe 3 + aq , Fe 2 + aq Pt s When the potential of the cell is 0 . 712 V at 298 K , the ratio Fe 2 + / Fe 3 + is (Nearest integer)

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99

The equilibrium constant for the reaction Zn s + Sn 2 + aq ⇌ Zn 2 + aq + Sn s is 1 × 10 20 at 298 K . The magnitude of standard electrode potential of Sn / Sn 2 + if E Z

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100

The standard electrode potential ( M 3 + / M 2 + ) for V , Cr , Mn & Co are - 0 . 26 V , - 0 . 41 V , + 1 . 57 V and + 1 . 97 V , respectively. The metal ions which can liberate H

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101

Following figure shows dependence of molar conductance of two electrolytes on concentration. Λ m 0 is the limiting molar conductivity. The number of Incorrect statement(s) fro

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102

Pt ( s ) H 2 ( g ) ( 1 bar ) H + ( aq ) ( 1 M ) M 3 + ( aq ) , M + ( aq ) Pt ( s ) The E cell for the given cell is 0 . 1115 V at 298 K When M + ( aq ) M 3 + ( aq ) = 10 a The valu

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103

Consider the cell Pt ( s ) H 2 ( s ) ( latm ) H + aq , H + = 1 | | Fe 3 + ( aq ) , Fe 2 + ( aq ) ∣ Pt ( s ) Given: E Fe 3 + / Fe 2 + ° = 0 . 771 V and E H + / 1 2 H 2 &#

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104

At 298 K , a 1 litre solution containing 10 mmol of Cr 2 O 7 2 - and 100 mmol of Cr 3 + shows a pH of 3 . 0 . Given : Cr 2 O 7 → 2 - Cr 3 + ; E 0 = 1 . 330 V and 2 . 303 RT F

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105

Consider the strong electrolytes Z m X n , U m Y p and V m X n . Limiting molar conductivity of U m Y p and V m X n are 250 and 440 S cm 2 mol - 1 , respectively. The value of m +

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106

The reduction potential E 0 , in V of MnO 4 - aq / Mn s is [Given: E MnO 4 - aq / MnO 2 s o = 1 . 68   V ;   E MnO 2 s / Mn 2 + aq o = 1 . 21   V ;     E M

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107

For a cell, Cu s Cu 2 + 0 . 001 M ) Ag + 0 . 01 M Ag s the cell potential is found to be 0 . 43 V at 298 K . The magnitude of standard electrode potential for Cu 2 + | Cu is____ &#

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108

Resistance of a conductivity cell (cell constant 129 m - 1 ) filled with 74 . 5 ppm solution of KCl is 100 Ω (labelled as solution 1 ). When the same cell is filled with KCl s

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109

Match List-I with List-II. List-I List-II A Cd s + 2 Ni OH 3 s → CdO s + 2 Ni OH 2 s + H 2 O l I Primary battery B Zn Hg + HgO s → ZnO s + Hg l II Discharging of second

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110

Given below are two statements: Statement I: For KI , molar conductivity increases steeply with dilution. Statement II: For carbonic acid, molar conductivity increases slowly with

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111

The amount of charge in F (Faraday) required to obtain one mole of iron from Fe 3 O 4 is ______. (Round off the answer to the nearest integer)

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112

The molar conductivity of a conductivity cell filled with 10 moles of 20 mL NaCl solution is Λ m 1 and that of 20 moles another identical cell heaving 80 mL NaCl solution is &

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113

The cell potential for Zn Zn 2 + ( aq ) ‖ Sn x + Sn is 0 . 801 V at 298 K . The reaction quotient for the above reaction is 10 - 2 . The number of electrons involved in the g

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114

The cell potential for the given cell at 298   K   Pt H 2 g , 1   bar H + aq ‖ Cu 2 + aq Cu s is 0 . 31   V . The pH of the acidic solution is found to be

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115

A dilute solution of sulphuric acid is electrolysed using a current of 0 . 10 A for 2 hours to produce hydrogen and oxygen gas. The total volume of gases produced at STP is cm 3 .

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116

For the given reactions Sn 2 + + 2 e - → Sn Sn 4 + + 4 e - → Sn the electrode potentials are ; E Sn 2 + / Sn ° = - 0 . 140   V and E Sn 4 + / Sn ° = 0 .

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117

The solubility product of a sparingly soluble salt A 2 X 3 is 1 . 1 × 10 - 23 . If specific conductance of the solution is 3 × 10 - 5 Sm - 1 , the limiting molar conducti

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118

The quantity of electricity in Faraday needed to reduce 1 mol of Cr 2 O 7 2 - to Cr 3 + is

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119

In 3 d series, the metal having the highest M 2 + / M standard electrode potential is

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120

For the reaction taking place in the cell: Pt s H 2 g H + aq Ag + aq Ag s E cell ° = + 0 . 5332 V . The value of Δ f G ⊖ is kJmol - 1 . (in nearest integer)

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