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JEE Main 20264 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2026 · 4 April · Evening Shift · Chemistry · Electrochemistry

An electrochemical cell, consist of the following two redox...

An electrochemical cell, consist of the following two redox couples, Mx+(aq)/M(s)M^{x+}(aq)/M(s) [Ered⊖=+0.15 V][E_{red}^\ominus=+0.15\text{ V}] and Fe3+(aq)/Fe(s)Fe^{3+}(aq)/Fe(s) [Ered⊖=−0.036 V][E_{red}^\ominus=-0.036\text{ V}]. The cell EMF (Ecell)(E_{cell}) is recorded to be 0.20570.2057 V. If the reaction quotient of the electrochemical reaction is found to be 10−210^{-2}, then the value of xx is ______. (Nearest integer)
[Given: M is a p-block metal and 2.303RTF=0.059\dfrac{2.303RT}{F}=0.059 V]

Correct answer

0

Step-by-step solution

Given standard reduction potentials:
EMx+/M⊖=+0.15E^{\ominus}_{M^{x+}/M} = +0.15 V
EFe3+/Fe⊖=−0.036E^{\ominus}_{Fe^{3+}/Fe} = -0.036 V

Since EMx+/M⊖>EFe3+/Fe⊖E^{\ominus}_{M^{x+}/M} > E^{\ominus}_{Fe^{3+}/Fe}, reduction occurs at the Mx+/MM^{x+}/M electrode (cathode) and oxidation occurs at the Fe3+/FeFe^{3+}/Fe electrode (anode).

Cathode reaction: (Mx++xe−→M)×3(M^{x+} + x e^{-} \rightarrow M) \times 3
Anode reaction: (Fe→Fe3++3e−)×x(Fe \rightarrow Fe^{3+} + 3 e^{-}) \times x

Overall balanced cell reaction:
3Mx++xFe→3M+xFe3+3 M^{x+} + x Fe \rightarrow 3 M + x Fe^{3+}

The number of electrons transferred in the balanced reaction is n=3xn = 3x.

Standard cell potential Ecell⊖E^{\ominus}_{cell} is:
Ecell⊖=Ecathode⊖−Eanode⊖E^{\ominus}_{cell} = E^{\ominus}_{cathode} - E^{\ominus}_{anode}
Ecell⊖=0.15−(−0.036)=0.186E^{\ominus}_{cell} = 0.15 - (-0.036) = 0.186 V

Using the Nernst equation:
Ecell=Ecell⊖−2.303RTnFlog⁡QE_{cell} = E^{\ominus}_{cell} - \dfrac{2.303RT}{nF} \log Q

Substitute the given values (Ecell=0.2057E_{cell} = 0.2057 V, Q=10−2Q = 10^{-2}, and 2.303RTF=0.059\dfrac{2.303RT}{F} = 0.059 V):
0.2057=0.186−0.0593xlog⁡(10−2)0.2057 = 0.186 - \dfrac{0.059}{3x} \log(10^{-2})

0.2057−0.186=−0.0593x×(−2)0.2057 - 0.186 = -\dfrac{0.059}{3x} \times (-2)

0.0197=0.1183x0.0197 = \dfrac{0.118}{3x}

3x=0.1180.01973x = \dfrac{0.118}{0.0197}

3x≈63x \approx 6

x=2x = 2

Answer: 22
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