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JEE Advanced 2011Paper 1
Exam
JEE Advanced
Year
2011
Paper
Paper 1
Subject
Chemistry
Chapter
Electrochemistry

JEE Advanced 2011 · Paper 1 · Chemistry · Electrochemistry

AgNO_3(a q) was added to an aqueous KCl solution gradually and the...

AgNO3(aq)\mathrm{AgNO}_3(a q) was added to an aqueous KCl\mathrm{KCl} solution gradually and the conductivity of the solution was measured. The plot of conductance (Λ)(\Lambda) versus the volume of AgNO3\mathrm{AgNO}_3 is AgNO_3(a q) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. The plot

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Correct answer

D. SS

Step-by-step solution

As AgNO3\mathrm{AgNO}_3 is added to solution, KCl\mathrm{KCl} will be displaced accrding to following reaction \mathrm{AgNO}}_{3}(a q)+ \mathrm{KCl}(a q) \longrightarrow \operatorname{AgCl}(s)+ \mathrm{KNO}}_{3}(a q) For every mole of KCl\mathrm{KCl} displaced from solution, one mole of KNO3\mathrm{KNO}_3 comes in solution resulting in almost constant conductivity. As the end point is reached, added AgNO3\mathrm{AgNO}_3 remain in solution increasing ionic concentration, hence conductivity increases.
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