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JEE Advanced 2025Paper 1
Exam
JEE Advanced
Year
2025
Paper
Paper 1
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JEE Advanced 2025 · Paper 1 · Chemistry · Haloalkanes and Haloarenes

For the reaction sequence given below, the correct statement(s)...

For the reaction sequence given below, the correct statement(s) is(are) For the reaction sequence given below, the correct statement(s) is(are) (In the options, X is any atom other than
(In the options, XX is any atom other than carbon and hydrogen, and it is different in P,Q\mathbf{P}, \mathbf{Q} and R\mathbf{R} )

Options

  1. AC-X bond length in P,Q\mathbf{P}, \mathbf{Q} and R\mathbf{R} follows the order Q>R>P\mathbf{Q}>\mathbf{R}>\mathbf{P}.
  2. BC-X bond enthalpy in P,Q\mathbf{P}, \mathbf{Q} and R\mathbf{R} follows the order R>P>Q\mathbf{R}>\mathbf{P}>\mathbf{Q}.
  3. CRelative reactivity toward SN2\mathrm{S}_{\mathrm{N}} 2 reaction in P,Q\mathbf{P}, \mathbf{Q} and R\mathbf{R} follows the order P>R>Q\mathbf{P}>\mathbf{R}>\mathbf{Q}.
  4. DpKa\mathrm{p} K_{\mathrm{a}} value of the conjugate acids of the leaving groups in P,Q\mathbf{P}, \mathbf{Q} and R\mathbf{R} follows the order R>Q>P\mathbf{R}>\mathbf{Q}>\mathbf{P}.

Correct answer

B. C-X bond enthalpy in P,Q\mathbf{P}, \mathbf{Q} and R\mathbf{R} follows the order R>P>Q\mathbf{R}>\mathbf{P}>\mathbf{Q}.

Step-by-step solution

For the reaction sequence given below, the correct statement(s) is(are) (In the options, X is any atom other than
(A) Wrong: bond length order Q>P>R\mathrm{Q}>\mathrm{P}>\mathrm{R} (B) Correct: Bond enthalpy R>P>Q\mathrm{R}>\mathrm{P}>\mathrm{Q} (C) Wrong: SN2\mathrm{S}_{\mathrm{N}} 2 reactivity Q>P>R\quad \mathrm{Q}>\mathrm{P}>\mathrm{R} (D) Wrong: pKa(HI<HBr<HF)R>\mathrm{pKa}(\mathrm{HI} <\mathrm{HBr} <\mathrm{HF}) \quad \mathrm{R}> P >Q(pKa)>\mathrm{Q}(\mathrm{pKa})
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