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JEE Advanced2025ChemistryHaloalkanes and HaloarenesActual

For the reaction sequence given below, the correct statement(s) is(are) (In the options, X is any atom other than carbon and hydrogen, and it is different in P , Q and R )

Options

  1. AC-X bond length in P , Q and R follows the order Q > R > P .
  2. BC-X bond enthalpy in P , Q and R follows the order R > P > Q .
  3. CRelative reactivity toward S _ N 2 reaction in P , Q and R follows the order P > R > Q .
  4. Dp K_ a value of the conjugate acids of the leaving groups in P , Q and R follows the order R > Q > P .

Correct answer

B. C-X bond enthalpy in P , Q and R follows the order R > P > Q .

Step-by-step solution

(A) Wrong: bond length order Q > P > R (B) Correct: Bond enthalpy R > P > Q (C) Wrong: S _ N 2 reactivity Q > P > R (D) Wrong: pKa ( HI P > Q ( pKa )

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