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JEE Advanced 2010Paper 1
Exam
JEE Advanced
Year
2010
Paper
Paper 1
Subject
Chemistry
Chapter
Hydrogen

JEE Advanced 2010 · Paper 1 · Chemistry · Hydrogen

The reagent(s) used for softening the temporary hardness of water...

The reagent(s) used for softening the temporary hardness of water is(are)

Options

  1. ACa3(PO4)2\mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2
  2. BCa(OH)2\mathrm{Ca}(\mathrm{OH})_2
  3. CNa2CO3\mathrm{Na}_2 \mathrm{CO}_3
  4. DNaOCl\mathrm{NaOCl}

Correct answer

B. Ca(OH)2\mathrm{Ca}(\mathrm{OH})_2

Step-by-step solution

Softening the temporary hardness of water means conversion of bicarbonate into calcium carbonate (precipitation) \begin{gathered}\mathrm{Ca}\left(\mathrm{HCO}_{3}\right)_2+ \mathrm{Ca}(\mathrm{OH})_2 \longrightarrow \\ 2 \mathrm{CaCO}_{3} \downarrow+2 \mathrm{H}_{2} \mathrm{O}\\ \mathrm{Ca}\left(\mathrm{HCO} }_{3}\right)_2+\mathrm{Na}_{2} \mathrm{CO}_{3} \longrightarrow \\ \mathrm{CaCO}_{3} \downarrow+2 \mathrm{NaHCO} }_{3} \end{gathered} Even \mathrm{NaOCl} can be used, as in aqueous medium O‾Cl\overline{\mathrm{O}} \mathrm{Cl} gets hydrolysed and makes solution alkaline enough to cause precipitation of CaCO3.\mathrm{CaCO}_3 .\begin{aligned}\mathrm{NaOCl}+\mathrm{H}_{2} \mathrm{O}& \rightleftharpoons \mathrm{HOCl}+\mathrm{NaOH}\\ \mathrm{OH}^{-}+\mathrm{HCO} }_{3}^{-} & \longrightarrow \mathrm{CO}_{3}^{2-}+ \mathrm{H}_{2} \mathrm{O} \end{aligned}$$ Representative elements (Hydrogen and its compounds) Conceptual II
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