Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Advanced 2026Paper 1
Exam
JEE Advanced
Year
2026
Paper
Paper 1
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Advanced 2026 · Paper 1 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Correct statement(s) about the compounds X , Y and Z is(are)

Correct statement(s) about the compounds X\textbf{X}, Y\textbf{Y} and Z\textbf{Z} is(are)
Correct statement(s) about the compounds X , Y and Z is(are)

Options

  1. AX\textbf{X} is used for sterilizing drinking water.
  2. BY\textbf{Y} has a planar structure.
  3. CZ\textbf{Z} is used in the enrichment of 235U^{235}\text{U}.
  4. DY\textbf{Y} is a stronger Lewis base than ammonia.

Correct answer

A. X\textbf{X} is used for sterilizing drinking water.

Step-by-step solution

From the given reactions, we can identify the compounds X\textbf{X}, Y\textbf{Y}, and Z\textbf{Z} as follows:

Reaction 1: MnO2+4HCl (conc.)→MnCl2+Cl2+2H2O\text{MnO}_2 + 4\text{HCl (conc.)} \rightarrow \text{MnCl}_2 + \text{Cl}_2 + 2\text{H}_2\text{O}
The greenish-yellow gas X\textbf{X} is Cl2\text{Cl}_2.

Reaction 2: NH3+3Cl2 (excess)→NCl3+3HCl\text{NH}_3 + 3\text{Cl}_2 \text{ (excess)} \rightarrow \text{NCl}_3 + 3\text{HCl}
Compound Y\textbf{Y} is NCl3\text{NCl}_3.

Reaction 3: Cl2+3F2 (excess)→573 K2ClF3\text{Cl}_2 + 3\text{F}_2 \text{ (excess)} \xrightarrow{573\text{ K}} 2\text{ClF}_3
Compound Z\textbf{Z} is ClF3\text{ClF}_3.

Evaluating the given statements:
(A) Cl2\text{Cl}_2 is widely used as a disinfectant for sterilizing drinking water. This statement is correct.

(B) In NCl3\text{NCl}_3, the nitrogen atom is sp3sp^3 hybridized and possesses one lone pair of electrons. This gives it a trigonal pyramidal structure, not a planar one. This statement is incorrect.

(C) ClF3\text{ClF}_3 is used in the enrichment of 235U^{235}\text{U} because it reacts with uranium to produce the volatile compound UF6\text{UF}_6 (U+3ClF3→UF6+3ClF\text{U} + 3\text{ClF}_3 \rightarrow \text{UF}_6 + 3\text{ClF}). This statement is correct.

(D) NCl3\text{NCl}_3 is a weaker Lewis base than NH3\text{NH}_3. The highly electronegative chlorine atoms withdraw electron density from the nitrogen atom via the -I effect, making the lone pair less available for donation compared to ammonia. This statement is incorrect.

Answer: X\textbf{X} is used for sterilizing drinking water.; Z\textbf{Z} is used in the enrichment of 235U^{235}\text{U}.
Practice p Block Elements (Group 15, 16, 17 & 18) on Quantrex Academy →

More from p Block Elements (Group 15, 16, 17 & 18)

Correct statement(s) about the compounds P , Q and R is(are) JEE Advanced 2026Find the correct statements related to group 15 hydrides. A. Reducing nature increases… JEE Main 2026Treatment of a gas ' X ' with a freshly prepared ferrous sulphate solution gives a… JEE Main 2026Correct statements from the following are: A. Nitrogen in oxidation states from +1 to +4… JEE Main 2026Given below are two statements: Statement I: The covalency of oxygen is generally two but… JEE Main 2026Given below are two statements : Statement (I) : Oxidising power of halogens decreases in… JEE Main 2026Given below are two statements : Statement I : The increasing order of boiling point of… JEE Main 2026Regarding the hydrides of group 15 elements EH_ 3 (E=N, P, As, Sb) , select the correct… JEE Main 2026 Full p Block Elements (Group 15, 16, 17 & 18) list All JEE Advanced PYQs