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JEE Main 20265 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
5 April
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2026 · 5 April · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Correct statements from the following are: A. Nitrogen in oxidation...

Correct statements from the following are:
A. Nitrogen in oxidation states from +1+1 to +4+4 disproportionates in acid medium.
B. Nitrogen has the ability to form dπ−pπd\pi - p\pi multiple bonds with itself and other elements with small size and high electronegativity.
C. N-N single bond is stronger than P-P single bond.
D. Nitrogen has highest density in its group due to small size.
E. The maximum covalency of nitrogen is four since it has only four valence orbitals for bonding.
Choose the correct answer from the options given below:

Options

  1. AB, C and D Only
  2. BC, D and E Only
  3. CA, C and E Only
  4. DA and E Only

Correct answer

D. A and E Only

Step-by-step solution

Statement A is correct. Nitrogen in oxidation states from +1+1 to +4+4 tends to disproportionate in acidic medium. For example, 3HNO2→HNO3+H2O+2NO3HNO_2 \rightarrow HNO_3 + H_2O + 2NO.

Statement B is incorrect. Nitrogen does not have d-orbitals in its valence shell, so it cannot form dπ−pπd\pi - p\pi multiple bonds. It forms pπ−pπp\pi - p\pi multiple bonds.

Statement C is incorrect. The N-N single bond is weaker than the P-P single bond due to high interelectronic repulsion between the non-bonding electrons, which arises from the small N-N bond length.

Statement D is incorrect. Density increases down the group in group 15. Nitrogen is a gas and has the lowest density in its group, while bismuth has the highest.

Statement E is correct. Nitrogen has only four valence orbitals (one 2s and three 2p orbitals) available for bonding. Therefore, its maximum covalency is restricted to four.

Thus, only statements A and E are correct.

Answer: A and E Only
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