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JEE Main 20264 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2026 · 4 April · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Given below are two statements: Statement I: The covalency of...

Given below are two statements:

Statement I: The covalency of oxygen is generally two but it can exceed upto four. The oxidation state of oxygen in SO2SO_2 is −2-2 and in OF2OF_2 it is +2+2.

Statement II: The anomalous behaviour of oxygen when compared to the other elements of group 1616 is due to its small size and high electronegativity.

In the light of the above statements, choose the correct answer from the options given below

Options

  1. ABoth Statement I and Statement II are true
  2. BBoth Statement I and Statement II are false
  3. CStatement I is true but Statement II is false
  4. DStatement I is false but Statement II is true

Correct answer

A. Both Statement I and Statement II are true

Step-by-step solution

Statement I: The electronic configuration of oxygen is 1s22s22p41s^{2} 2s^{2} 2p^{4}. Due to the absence of d-orbitals, its maximum covalency is limited to four (using one 2s and three 2p orbitals). Its covalency is generally two, but it can exceed two and go up to four in certain compounds. In SO2SO_2, oxygen is more electronegative than sulphur, so its oxidation state is −2-2. In OF2OF_2, fluorine is more electronegative than oxygen, so the oxidation state of oxygen is +2+2. Thus, Statement I is true.

Statement II: Oxygen differs from the rest of the group 16 elements due to its small atomic size, high electronegativity, and the absence of d-orbitals in its valence shell. This leads to its anomalous behaviour, such as the ability to form strong hydrogen bonds and pπ−pπp\pi-p\pi multiple bonds. Thus, Statement II is true.

Both Statement I and Statement II are true.

Answer: Both Statement I and Statement II are true
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