JEE Advanced 2015Paper 2
- Exam
- JEE Advanced
- Year
- 2015
- Paper
- Paper 2
- Subject
- Chemistry
- Chapter
- Redox Reactions
JEE Advanced 2015 · Paper 2 · Chemistry · Redox Reactions
When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an...
When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of was measured for the beaker and its contents (Expt.1). Because the enthalpy of neutralization of a strong acid with a strong base is a constant , this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2), 100 mL of 2.0 M acetic acid was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of was measured. (Consider heat capacity of all solutions as and density of all solutions as )
Enthalpy of dissociation of acetic acid obtained from the Expt. 2 is
Enthalpy of dissociation of acetic acid obtained from the Expt. 2 is
Options
- A
- B
- C
- D
Correct answer
A.
Step-by-step solution
Let the heat capacity of insulated beaker be C.
Mass of aqueous content in Expt. 1
Moles of acid, base neutralized in Expt. 1
Heat absorbed in Expt. 1
In Second experiment
Total mass of aqueous content = 200 g
Total heat capacity
Heat released
Overall, only 0.1 mol of undergo neutralization.
Mass of aqueous content in Expt. 1
Moles of acid, base neutralized in Expt. 1
Heat absorbed in Expt. 1
In Second experiment
Total mass of aqueous content = 200 g
Total heat capacity
Heat released
Overall, only 0.1 mol of undergo neutralization.